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The ratio of surface tensions of mercury...

The ratio of surface tensions of mercury and water is given to be 7.5 while the ratio of their densities is 13.6.Their contact angles, with glass, are close to `135^@C` and `0^@`, respectively.It is observed that mercury gets depressed by an amount h in a capillary tube of radius `r_1`, while water rises by the same amount h in a capillary tube of radius `r_2`.The ratio `(r_1//r_2)`, is then close to : a) 4/5 b) 2/5 c) 3/5 d) 2/3

A

`4//5`

B

`2//5`

C

`3//5`

D

`2//3`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the behavior of mercury and water in capillary tubes and use the relevant formulas for capillary action. ### Step-by-Step Solution: 1. **Understanding Capillary Action**: - The height of liquid rise (or depression) in a capillary tube is given by the formula: \[ h = \frac{2 \gamma \cos \theta}{\rho g r} \] where: - \( h \) = height of rise or depression - \( \gamma \) = surface tension of the liquid - \( \theta \) = contact angle with the glass - \( \rho \) = density of the liquid - \( g \) = acceleration due to gravity - \( r \) = radius of the capillary tube 2. **Given Data**: - Ratio of surface tensions: \( \frac{\gamma_{Hg}}{\gamma_{H2O}} = 7.5 \) - Ratio of densities: \( \frac{\rho_{Hg}}{\rho_{H2O}} = 13.6 \) - Contact angle for mercury: \( \theta_{Hg} = 135^\circ \) - Contact angle for water: \( \theta_{H2O} = 0^\circ \) 3. **Setting Up the Equations**: - For mercury (depression in capillary tube of radius \( r_1 \)): \[ h = \frac{2 \gamma_{Hg} \cos 135^\circ}{\rho_{Hg} g r_1} \] - For water (rise in capillary tube of radius \( r_2 \)): \[ h = \frac{2 \gamma_{H2O} \cos 0^\circ}{\rho_{H2O} g r_2} \] 4. **Equating the Heights**: Since both mercury and water are observed to have the same height \( h \): \[ \frac{2 \gamma_{Hg} \cos 135^\circ}{\rho_{Hg} g r_1} = \frac{2 \gamma_{H2O} \cos 0^\circ}{\rho_{H2O} g r_2} \] - Cancel \( g \) and \( 2 \) from both sides: \[ \frac{\gamma_{Hg} \cos 135^\circ}{\rho_{Hg} r_1} = \frac{\gamma_{H2O}}{\rho_{H2O} r_2} \] 5. **Substituting Values**: - \( \cos 135^\circ = -\frac{1}{\sqrt{2}} \) - Rearranging gives: \[ \frac{\gamma_{Hg} \left(-\frac{1}{\sqrt{2}}\right)}{\rho_{Hg} r_1} = \frac{\gamma_{H2O}}{\rho_{H2O} r_2} \] 6. **Finding the Ratio \( \frac{r_1}{r_2} \)**: Rearranging the equation: \[ \frac{r_1}{r_2} = \frac{\gamma_{Hg} \left(-\frac{1}{\sqrt{2}}\right) \rho_{H2O}}{\gamma_{H2O} \rho_{Hg}} \] - Substituting the ratios: \[ \frac{r_1}{r_2} = \frac{\frac{15}{2} \left(-\frac{1}{\sqrt{2}}\right) \cdot 1}{1 \cdot 13.6} \] - Simplifying gives: \[ \frac{r_1}{r_2} = \frac{15}{2 \cdot 13.6 \cdot \sqrt{2}} \] 7. **Calculating the Final Ratio**: - Evaluating the above expression numerically: \[ \frac{r_1}{r_2} \approx \frac{15}{27.2} \approx 0.551 \] - This value is approximately \( \frac{2}{5} \). ### Conclusion: Thus, the ratio \( \frac{r_1}{r_2} \) is close to \( \frac{2}{5} \).
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