Home
Class 12
CHEMISTRY
Which of the following is formed when 2 ...

Which of the following is formed when 2 butene is treated with alkaline `KMnO_(4)` higher temperature

A

`CH_(3) - underset(OH)underset(|) (CH) - underset(OH)underset(|) (CH) - CH_(3)`

B

one molecule of `CH_(3)CHO` and one molecule of `CH_(3)COOH`

C

`2` molecules of `CH_(3)COOH`

D

`2` molecules of `CH_(3)CHO`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of what is formed when 2-butene is treated with alkaline KMnO4 at high temperature, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure of 2-Butene**: - The molecular formula of 2-butene is C4H8. Its structure can be represented as: \[ \text{CH}_3-\text{CH}=\text{CH}-\text{CH}_3 \] - This shows that there is a double bond between the second and third carbon atoms. 2. **Understand the Reaction Conditions**: - The reagent is alkaline KMnO4, which is a strong oxidizing agent. The reaction is carried out at high temperature. 3. **Reaction Mechanism**: - The KMnO4 will insert an oxygen atom into the double bond of 2-butene. This is known as syn-dihydroxylation. - The reaction can be illustrated as: \[ \text{CH}_3-\text{CH}=\text{CH}-\text{CH}_3 \xrightarrow{\text{KMnO}_4} \text{CH}_3-\text{C(OH)}-\text{C(OH)}-\text{CH}_3 \] - This results in the formation of a diol (a compound with two hydroxyl groups). 4. **Rearrangement and Oxidation**: - Under the conditions of high temperature and the presence of KMnO4, the diol can undergo further oxidation. - The hydroxyl groups can be oxidized to form carbonyl groups (aldehydes), leading to the formation of acetic acid (CH3COOH) when further oxidized. 5. **Final Products**: - The final products of the reaction are two molecules of acetic acid: \[ 2 \text{CH}_3\text{COOH} \] ### Conclusion: The correct answer is that when 2-butene is treated with alkaline KMnO4 at high temperature, it forms two molecules of acetic acid (CH3COOH).
Promotional Banner

Topper's Solved these Questions

  • JEE MAINS

    JEE MAINS PREVIOUS YEAR ENGLISH|Exercise QUESTION|1 Videos
  • JEE MAIN

    JEE MAINS PREVIOUS YEAR ENGLISH|Exercise CHEMISTRY|146 Videos
  • JEE MAINS 2020

    JEE MAINS PREVIOUS YEAR ENGLISH|Exercise CHEMSITRY|23 Videos

Similar Questions

Explore conceptually related problems

Acetylene react with alkaline KMnO_(4) to give

Which of the following compounds are formed when BCI_(3) is treated with water?

Which of the following is the product formed when phenol is treated with dilute nitric acid ?

Which of the following compound will give butanone on oxidation with alkaline KMnO_(4) solution ?

Which of the following compound will give butanone on oxidation with alkaline KMnO_(4) solution ?

Which of the following compounds will give butanone on oxidation with alkaline KMnO_(4) solution ?