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The number of stereoisomers possible fo...

The number of stereoisomers possible for a compound of the molecular formula `CH_(3)-CH=CH-CH(OH)-Me` is

A

3

B

2

C

4

D

6

Text Solution

AI Generated Solution

The correct Answer is:
To determine the number of stereoisomers for the compound with the molecular formula `CH3-CH=CH-CH(OH)-CH3`, we will follow these steps: ### Step 1: Identify the Structure The compound can be represented as: - CH3-CH=CH-CH(OH)-CH3 This indicates that we have a 5-carbon chain with a double bond between the second and third carbons and a hydroxyl (OH) group on the fourth carbon. ### Step 2: Identify the Double Bond The double bond between the second and third carbons (C2=C3) can give rise to geometric (cis/trans) isomerism. ### Step 3: Determine the Configuration of the Double Bond For the double bond C2=C3: - If both substituents on C2 and C3 are the same, it will not lead to stereoisomerism. - In our case, C2 has CH3 and CH (from CH(OH)-CH3) as substituents, and C3 has CH and CH3. Therefore, we can have two configurations: - **Cis**: Both CH3 groups are on the same side. - **Trans**: CH3 groups are on opposite sides. ### Step 4: Identify the Chiral Center The carbon atom at C4 (the one attached to the hydroxyl group) is a chiral center because it has four different substituents: 1. CH3 2. OH 3. CH (from the double bond) 4. H ### Step 5: Calculate the Total Number of Stereoisomers The number of stereoisomers can be calculated using the formula: \[ \text{Total Stereoisomers} = 2^n \] where \( n \) is the number of chiral centers plus the number of geometric isomers. - We have 1 chiral center (C4). - We have 2 geometric isomers (cis and trans for the double bond). Thus, the total number of stereoisomers is: \[ \text{Total Stereoisomers} = 2^1 \times 2 = 2 \times 2 = 4 \] ### Conclusion The number of stereoisomers possible for the compound `CH3-CH=CH-CH(OH)-CH3` is **4**. ---
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