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Which one of the following statements is...

Which one of the following statements is correct ?

A

(a) All amino acids except lysine are optically active

B

(b) All amino acids are optically active

C

(c) All amino acids except glycine are optically active

D

(d) All amino acids except glutamic acid are optically active

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement regarding amino acids is correct, we need to analyze the properties of amino acids, particularly focusing on their optical activity. Here's a step-by-step solution: ### Step 1: Understand the Structure of Amino Acids Amino acids have a general structure that includes: - An amino group (-NH2) - A carboxylic acid group (-COOH) - A hydrogen atom - A variable R group (side chain) The central carbon atom (alpha carbon) is attached to these four different groups. ### Step 2: Identify Optical Activity A compound is optically active if it has a chiral center, which means it must have four different groups attached to a carbon atom. If two of the groups are the same, the compound is achiral and optically inactive. ### Step 3: Analyze Each Statement 1. **Statement A**: "All amino acids except glycine are optically active." 2. **Statement B**: "All amino acids are optically active." 3. **Statement C**: "All amino acids except glycine are optically active." 4. **Statement D**: "All amino acids except glutamic acid are optically active." ### Step 4: Evaluate Each Statement - **Glycine**: The R group in glycine is a hydrogen atom (H), making it have two identical groups attached to the alpha carbon (NH2 and H). Therefore, glycine is **not optically active**. - **Other Amino Acids**: Most amino acids have four different groups attached to their alpha carbon, making them optically active. - **Statement A**: This is incorrect because it implies that glycine is the only exception, but it does not specify that glycine itself is optically inactive. - **Statement B**: This is incorrect because glycine is not optically active. - **Statement C**: This is correct. All amino acids except glycine are optically active. - **Statement D**: This is incorrect because glutamic acid is optically active. ### Conclusion The correct statement is **Statement C**: "All amino acids except glycine are optically active."
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