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If the series limit frequency of the Lym...

If the series limit frequency of the Lyman series is `v_(L)`, then the series limit frequency of the Pfund seriesis :

A

`v_(L)//25`

B

`25 v_(L)`

C

`16 v_(L)`

D

`v_(L)//16`

Text Solution

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The correct Answer is:
To find the series limit frequency of the Pfund series given the series limit frequency of the Lyman series, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Series Limit Frequencies**: The series limit frequency for a hydrogen atom transition can be calculated using the formula: \[ \nu \propto \frac{1}{n_f^2 - n_i^2} \] where \( n_f \) is the final energy level and \( n_i \) is the initial energy level. 2. **Identify the Values for Lyman Series**: For the Lyman series, the transitions end at \( n_f = 1 \) (ground state). The initial levels can be any \( n_i \geq 2 \). The series limit corresponds to the transition from \( n_i \to \infty \): \[ \nu_L \propto \frac{1}{1^2 - \infty^2} = \frac{1}{1 - \infty} \rightarrow \text{(approaches zero)} \] 3. **Identify the Values for Pfund Series**: For the Pfund series, the transitions end at \( n_f = 5 \). The initial levels can be any \( n_i \geq 6 \). The series limit corresponds to the transition from \( n_i \to \infty \): \[ \nu_P \propto \frac{1}{5^2 - \infty^2} = \frac{1}{25 - \infty} \rightarrow \text{(approaches zero)} \] 4. **Setting Up the Ratio**: To find the relationship between the frequencies of the two series: \[ \frac{\nu_P}{\nu_L} = \frac{1/(5^2 - \infty^2)}{1/(1^2 - \infty^2)} \] Simplifying this gives: \[ \frac{\nu_P}{\nu_L} = \frac{1/(25 - \infty)}{1/(1 - \infty)} = \frac{1/25}{1} = \frac{1}{25} \] 5. **Finding the Series Limit Frequency of Pfund**: If we denote the series limit frequency of the Lyman series as \( \nu_L \), then: \[ \nu_P = \nu_L \cdot \frac{1}{25} \] This means: \[ \nu_P = \frac{\nu_L}{25} \] ### Final Answer: Thus, the series limit frequency of the Pfund series is: \[ \nu_P = \frac{\nu_L}{25} \]
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