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A H–atom in ground state has time period...

A H–atom in ground state has time period `T = 1.6 xx 10^(–16)` sec. find the frequency of electron in first excited state

A

`7.8xx10^(14)`

B

`7.8xx10^(16)`

C

`3.7xx10^(14)`

D

`3.7xx10^(16)`

Text Solution

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The correct Answer is:
To find the frequency of the electron in the first excited state of a hydrogen atom, we can follow these steps: ### Step 1: Understand the relationship between time period and quantum number The time period \( T \) of an electron in a hydrogen atom is related to the quantum number \( n \). For a hydrogen atom, the time period can be expressed as: \[ T \propto n^3 \] This means that the time period increases with the cube of the quantum number \( n \). ### Step 2: Write the relationship for the ground state and first excited state Let \( T_1 \) be the time period for the ground state (\( n_1 = 1 \)) and \( T_2 \) be the time period for the first excited state (\( n_2 = 2 \)). We can express this relationship as: \[ \frac{T_1}{T_2} = \left(\frac{n_1}{n_2}\right)^3 \] Substituting \( n_1 = 1 \) and \( n_2 = 2 \): \[ \frac{T_1}{T_2} = \left(\frac{1}{2}\right)^3 = \frac{1}{8} \] This implies: \[ T_2 = 8 T_1 \] ### Step 3: Calculate the time period for the first excited state Given that the time period for the ground state \( T_1 = 1.6 \times 10^{-16} \) seconds, we can find \( T_2 \): \[ T_2 = 8 \times (1.6 \times 10^{-16}) = 12.8 \times 10^{-16} \text{ seconds} \] ### Step 4: Find the frequency The frequency \( f \) is the reciprocal of the time period \( T \): \[ f = \frac{1}{T} \] Thus, the frequency for the first excited state \( f_2 \) is: \[ f_2 = \frac{1}{T_2} = \frac{1}{12.8 \times 10^{-16}} \text{ Hz} \] ### Step 5: Calculate the frequency Calculating \( f_2 \): \[ f_2 = \frac{1}{12.8 \times 10^{-16}} \approx 7.8125 \times 10^{14} \text{ Hz} \] Rounding this to two significant figures, we get: \[ f_2 \approx 7.8 \times 10^{14} \text{ Hz} \] ### Final Answer The frequency of the electron in the first excited state is approximately: \[ \boxed{7.8 \times 10^{14} \text{ Hz}} \]
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