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Which of the following reaction will not...

Which of the following reaction will not form racemic mixture as product?

A

B

C

D

Text Solution

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The correct Answer is:
To determine which reaction will not form a racemic mixture, we need to analyze each reaction and identify whether the product contains a chiral center. A racemic mixture is formed when a reaction produces a chiral compound that can exist in two enantiomeric forms. ### Step-by-Step Solution: 1. **Understanding Racemic Mixtures**: - A racemic mixture consists of equal amounts of two enantiomers (mirror-image isomers). For a compound to be chiral, it must have four different substituents attached to a central carbon atom. 2. **Analyzing Reaction A**: - The reaction involves a carbonyl compound reacting with HCN to form a cyanohydrin. - The carbon atom that is formed during this reaction becomes chiral because it has four different groups attached to it (CH3, CH2, CN, and OH). - **Conclusion**: Reaction A will form a racemic mixture. 3. **Analyzing Reaction B**: - The reaction involves a compound with two identical methyl groups reacting with HCl. - The resulting carbocation has two identical groups (the two methyl groups), which means the carbon is not chiral. - **Conclusion**: Reaction B will not form a racemic mixture. 4. **Analyzing Reaction C**: - The reaction involves a cyclohexane ring with a double bond and a methyl group reacting with HCl. - The formation of a tertiary carbocation occurs, which is chiral due to having four different groups attached (methyl, hydrogen, chlorine, and the rest of the cyclohexane). - **Conclusion**: Reaction C will form a racemic mixture. 5. **Analyzing Reaction D**: - The reaction involves butene reacting with HBr. - A secondary carbocation is formed, which can also lead to a chiral center being formed depending on the attack of bromine. - The resulting product has four different groups attached to the chiral carbon. - **Conclusion**: Reaction D will form a racemic mixture. ### Final Answer: The reaction that will not form a racemic mixture is **Reaction B**.
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