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If a compound is AB4 is polar then its s...

If a compound is `AB_4` is polar then its strcture is similar to

A

Square planar

B

Tetrahedral

C

Trigonal bipyramidal

D

Rectangular planar

Text Solution

AI Generated Solution

The correct Answer is:
To determine the structure of a polar compound with the formula \( AB_4 \), we need to analyze the possible geometries and their effects on the dipole moment. ### Step-by-Step Solution: 1. **Understanding Polarity**: - A molecule is polar if it has a net dipole moment that is non-zero. This means that the dipole moments of the individual bonds do not cancel each other out. 2. **Identifying Possible Geometries**: - The possible geometries for \( AB_4 \) include: - Tetrahedral - Square planar - Trigonal bipyramidal 3. **Analyzing Square Planar Geometry**: - In a square planar geometry, the four \( B \) atoms are arranged in a square plane around the central atom \( A \). - If \( B \) is more electronegative than \( A \), the dipole moments from each \( B \) will point towards \( B \). - The dipole moments will cancel each other out due to symmetry, resulting in a net dipole moment of zero. Thus, a square planar structure is non-polar. 4. **Analyzing Tetrahedral Geometry**: - In a tetrahedral geometry, the four \( B \) atoms are arranged around the central atom \( A \) in a three-dimensional shape. - Similar to the square planar case, if \( B \) is more electronegative than \( A \), the dipole moments will also cancel out due to symmetry. - Therefore, a tetrahedral structure is also non-polar. 5. **Analyzing Trigonal Bipyramidal Geometry**: - In a trigonal bipyramidal geometry, there are five positions: three in a plane (equatorial) and two above and below the plane (axial). - If one of the positions is occupied by a lone pair, the geometry becomes distorted. - The dipole moments from the \( B \) atoms will not cancel out due to the presence of the lone pair, resulting in a net dipole moment that is non-zero. Hence, this structure can be polar. 6. **Conclusion**: - The only geometry among the options that can result in a polar molecule is the trigonal bipyramidal geometry with a lone pair. Therefore, the structure of the polar compound \( AB_4 \) is similar to that of a trigonal bipyramidal geometry. ### Final Answer: The structure of the polar compound \( AB_4 \) is similar to **trigonal bipyramidal**.
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