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Given i) A harr B+C K(eq)(1) ii)...

Given
`i) A harr B+C K_(eq)(1)
ii) B+C harr P K_(eq)(2)`
then `K_(eq)` for reaction `Aharrp`is

A

`K_(eq)(1).K_(eq)(2)`

B

`K_(eq)(1)//K_(eq)(2)`

C

`K_(eq)(1)+K_(eq)(2)`

D

`K_(eq)(1)-K_(eq)(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To find the equilibrium constant \( K_{eq} \) for the reaction \( A \rightleftharpoons P \), we will use the given reactions and their equilibrium constants. ### Step-by-Step Solution: 1. **Write the Given Reactions:** - Reaction 1: \( A \rightleftharpoons B + C \) with \( K_{eq} = K_{eq}(1) \) - Reaction 2: \( B + C \rightleftharpoons P \) with \( K_{eq} = K_{eq}(2) \) 2. **Reverse Reaction 2:** - To find the equilibrium constant for \( A \rightleftharpoons P \), we need to manipulate the given reactions. First, we reverse Reaction 2: \[ P \rightleftharpoons B + C \] - The equilibrium constant for the reversed reaction is the reciprocal of the original: \[ K_{eq} = \frac{1}{K_{eq}(2)} \] 3. **Add the Reactions:** - Now, we can add the modified Reaction 2 to Reaction 1: \[ A \rightleftharpoons B + C \quad (K_{eq} = K_{eq}(1)) \] \[ P \rightleftharpoons B + C \quad (K_{eq} = \frac{1}{K_{eq}(2)}) \] - When we add these two reactions, the \( B + C \) cancels out: \[ A \rightleftharpoons P \] 4. **Calculate the Overall Equilibrium Constant:** - According to the principle of equilibrium constants, when reactions are added, their equilibrium constants multiply: \[ K_{eq} = K_{eq}(1) \times \frac{1}{K_{eq}(2)} \] - Therefore, we can express the equilibrium constant for the reaction \( A \rightleftharpoons P \) as: \[ K_{eq} = \frac{K_{eq}(1)}{K_{eq}(2)} \] ### Final Answer: The equilibrium constant \( K_{eq} \) for the reaction \( A \rightleftharpoons P \) is: \[ K_{eq} = \frac{K_{eq}(1)}{K_{eq}(2)} \]
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