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Which statement is incorrect regarding L...

Which statement is incorrect regarding Lactose?

A

It is composed of `beta`-D(+)-Galactose & `beta`-D(+)-Glucose

B

It is a reducing sugar

C

It is a disaccharides `(C_12H_22O_11)` having eight -OH groups

D

It has glycosidic linkage of `C_1` of glucose & `C_4` OF galactose

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement is incorrect regarding lactose, we will analyze the provided options based on the structure and properties of lactose. ### Step-by-Step Solution: 1. **Understanding the Composition of Lactose**: - Lactose is a disaccharide composed of two monosaccharides: β-D-galactose and β-D-glucose. - Therefore, any statement claiming that lactose is made up of these two components is correct. **Hint**: Recall the basic structure of disaccharides and their monomeric units. 2. **Identifying Reducing Sugar**: - A reducing sugar is one that has a free aldehyde or ketone group capable of acting as a reducing agent. - In the case of lactose, both β-D-galactose and β-D-glucose have free anomeric hydroxyl groups, making lactose a reducing sugar. **Hint**: Check for free functional groups in the structure of the sugar to determine if it is reducing. 3. **Counting Hydroxyl Groups**: - To verify the number of hydroxyl (OH) groups in lactose, we can analyze its structure: - β-D-galactose has 4 OH groups. - β-D-glucose has 4 OH groups. - When combined, we need to consider the glycosidic bond, which connects the two sugars, effectively reducing the total count by one. - Thus, the total number of OH groups in lactose is 4 (from galactose) + 4 (from glucose) - 1 (due to the bond) = 7 OH groups. **Hint**: Count the OH groups in each monosaccharide and adjust for the glycosidic bond. 4. **Analyzing Glycosidic Linkage**: - The glycosidic linkage in lactose occurs between the C1 of β-D-galactose and the C4 of β-D-glucose. - If any statement claims otherwise, it would be incorrect. **Hint**: Remember the specific carbons involved in the glycosidic bond when analyzing the structure. 5. **Conclusion**: - Now, let’s summarize the statements: 1. Lactose is made up of β-D-galactose and β-D-glucose - **Correct**. 2. Lactose is a reducing sugar - **Correct**. 3. Lactose has 8 OH groups - **Incorrect** (it has 7). 4. Lactose has a glycosidic linkage between C1 of glucose and C4 of galactose - **Incorrect** (it is C1 of galactose and C4 of glucose). - The incorrect statement regarding lactose is that it has 8 OH groups. ### Final Answer: The incorrect statement regarding lactose is that it has 8 OH groups.
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