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In the line spectra of hydrogen atom, di...

In the line spectra of hydrogen atom, difference between the largest and the shortest wavelengths of the Lyman series is `340Å` . The corresponding difference of the Paschan series in `Å` is ...........

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To solve the problem of finding the difference between the largest and shortest wavelengths of the Paschen series in the hydrogen atom, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Series**: - The Lyman series corresponds to transitions where the final energy level (n_final) is 1. - The Paschen series corresponds to transitions where the final energy level (n_final) is 3. 2. **Wavelength Formula**: - The wavelength (λ) of the emitted light can be calculated using the Rydberg formula: \[ \frac{1}{\lambda} = R \left( \frac{1}{n_{final}^2} - \frac{1}{n_{initial}^2} \right) \] - Here, \( R \) is the Rydberg constant. 3. **Finding λ_min and λ_max for Lyman Series**: - For the Lyman series (n_final = 1): - The shortest wavelength (λ_min) occurs when n_initial is at its minimum, which is 2: \[ \frac{1}{\lambda_{min}} = R \left( \frac{1}{1^2} - \frac{1}{2^2} \right) = R \left( 1 - \frac{1}{4} \right) = R \left( \frac{3}{4} \right) \] \[ \lambda_{min} = \frac{4}{3R} \] - The longest wavelength (λ_max) occurs when n_initial approaches infinity: \[ \frac{1}{\lambda_{max}} = R \left( \frac{1}{1^2} - 0 \right) = R \] \[ \lambda_{max} = \frac{1}{R} \] 4. **Calculating the Difference for Lyman Series**: - The difference between the largest and shortest wavelengths for the Lyman series is given as 340 Å: \[ \lambda_{max} - \lambda_{min} = \frac{1}{R} - \frac{4}{3R} \] \[ = \frac{3}{3R} - \frac{4}{3R} = \frac{-1}{3R} \] - Therefore, we can set up the equation: \[ \frac{1}{3R} = 340 \Rightarrow R = \frac{1}{3 \times 340} \] 5. **Finding λ_min and λ_max for Paschen Series**: - For the Paschen series (n_final = 3): - The shortest wavelength (λ_min) occurs when n_initial is 4: \[ \frac{1}{\lambda_{min}} = R \left( \frac{1}{3^2} - \frac{1}{4^2} \right) = R \left( \frac{1}{9} - \frac{1}{16} \right) \] \[ = R \left( \frac{16 - 9}{144} \right) = \frac{7R}{144} \] \[ \lambda_{min} = \frac{144}{7R} \] - The longest wavelength (λ_max) occurs when n_initial approaches infinity: \[ \frac{1}{\lambda_{max}} = R \left( \frac{1}{3^2} - 0 \right) = \frac{R}{9} \] \[ \lambda_{max} = \frac{9}{R} \] 6. **Calculating the Difference for Paschen Series**: - The difference between the largest and shortest wavelengths for the Paschen series: \[ \lambda_{max} - \lambda_{min} = \frac{9}{R} - \frac{144}{7R} \] \[ = \frac{63 - 144}{7R} = \frac{-81}{7R} \] 7. **Finding the Corresponding Difference**: - We know that the difference for the Lyman series is 340 Å, so we can set up the ratio: \[ \frac{\lambda_{max} - \lambda_{min} \text{ (Paschen)}}{\lambda_{max} - \lambda_{min} \text{ (Lyman)}} = \frac{-81/7R}{-1/3R} \] \[ = \frac{81 \times 3}{7} = \frac{243}{7} \] - Therefore, the difference for the Paschen series is: \[ \lambda_{max} - \lambda_{min} \text{ (Paschen)} = 340 \times \frac{243}{7} \approx 1176.43 \text{ Å} \] ### Final Answer: The corresponding difference of the Paschen series is approximately **1176.43 Å**.
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