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The electronic spectrum of [Ti(H(2)O)(6)...

The electronic spectrum of `[Ti(H_(2)O)_(6)]^(3+)` shows a single broad peak with a maximum at `"20,300 cm"^(-1)`.
The crystal field stabillization energy (CFSE) of the complex ion, in `"kJ mol"^(-1)`, is :
`("1 kJ mol"^(-1) =" 83.7 cm"^(-1))`

A

83.7

B

242.5

C

145.5

D

97

Text Solution

Verified by Experts

The correct Answer is:
D
`[Ti^(2+)(H_(2)O)_(6)]^(3+)Ti^(3+)3d^(1)` in octahedral field of ligend

CFSE `=-0.4Delta_(0)`
`CFSE=(-.4xx20300)/(83.7)`
= 97 kJ mol
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