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Standard entropies of x(2) , y(2) and xy...

Standard entropies of `x_(2) , y_(2) and xy_(3)` are `60,40 and 50 "J/K mol"^(-1)` respectively for the reaction `(1)/(2) x_(2) + (3)/(2) y_(2) to xy_(3) , Delta H = - 30 "kJ"` to be at equilibrium the temperature should be.

A

500 K

B

750 K

C

1000 K

D

1250 K

Text Solution

Verified by Experts

The correct Answer is:
B

`Delta S = 50 - ((60)/(2) + (3)/(2) xx 40)`
`= 50 (30+ 60) = - 40 "J/K mol"`
`Delta G = 0`
`therefore Delta H = T Delta S therefore T = (-30 xx 10^(3) )/( - 40) = 750 K`
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