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Stoichiometric Calculation

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why is Fe0(s) not formed in stoichiometric compostion ?

Analyses shows that FeO has a non-stoichiometric composition with formula Fe_(0.95)O_(1.00) . Give reason.

Stoichiometric ratio of sodium dihydrogen orthophosphate and sodium hydrogen orthophosphate required for synthesis of Na_(5) P_(3) O_(10) is