Home
Class 11
CHEMISTRY
What is the stability order of various a...

What is the stability order of various alkyl free radicals ? Why?

Text Solution

Verified by Experts

The stability order of alkyl free radicals is:
`underset(3^0)((CH_3)_(3))overset(*)Cgtunderset(3^0)((CH_3)_(2))overset(*)CHgtunderset(1^0)(CH_3)overset(*)CH_2gtCH_3`
More the number of hyperconjugative structures , the greater is the stability . Tertiary butyl free radical has 9, Isopropyl free radical has 6, cthyl free radical has 3 and methyl free radical has no hyper-conjugative structures.
Promotional Banner

Topper's Solved these Questions

  • ELECTRON MIGRATION EFFECTS

    AAKASH SERIES|Exercise EXERCISE 2 . 1.1|4 Videos
  • ELECTRON MIGRATION EFFECTS

    AAKASH SERIES|Exercise EXERCISE 2 . 1.2|5 Videos
  • CHEMICAL THERMODYNAMICS

    AAKASH SERIES|Exercise PRACTICE EXERCISE|50 Videos
  • ELECTRONIC EFFECTS AND REACTION INTERMEDIATES

    AAKASH SERIES|Exercise ADDITIONAL PRACTICE EXERCISE (LEVEL - II (PRACTICE SHEET ADVANCE)) (Integer Type Questions)|3 Videos

Similar Questions

Explore conceptually related problems

The stability order of alkyl free radicals can be explained by hyperconjugation

The stability order of alkyl free radicals is: (CH_(3))_(3) overset(.)C gt (CH_(3))_(2) overset(.)CH gt CH_(3) overset(.)CH_(2) gt overset(.)CH_(3)

What is the stability order of the VA group hydrides ? Explain the gradation in the reducing property of these hydrides.

What is the stability order of these elements in their compounds in +2 oxidation states? Why?

The stability order of following carbocation is

What is an alkyl group?

Which of the following is a free radical?

In this polymerization reaction, growing polystyrene radical which normally would add on a polymer reacts with te chain transfer agent to end the original chain What is the initator in the vinylic free radical polymerization ?

Stability of alkenes, carbocations, alkyl free radicals, orienting effect of alkyl groups in aromatic ring, unexpected bond lengths in some molecules, etc. can be explained by hyperconjugation