Home
Class 11
CHEMISTRY
Show that the role of cone, sulphuric ac...

Show that the role of cone, sulphuric acid is not a dehydrating agent, but used for production of nitronium cation. 

Text Solution

Verified by Experts

Nitration mixture is a mixture of conc. nitric acid and conc. sulphuric acid. Sulphuric acid acts as an acid and donates a proton to nitric acid. The protonated nitric acid, gives nitronium cation by the loss of water molecule.
`HHSO_(4)+HNO_(3) to HSO_(4)^(-)+H_(2)O^(+) -NO_(2) , H_(2) overset(+)(O) NO_(2) to NO_(2)^(+)+ H_(2)O`
Benzene gives nitorbenzene by electrophilic substitution.
`C_(6)H_(6)+NO_(2)^(+) to C_(6)H_(5)NO_(2)+H^(+) , H^(+)+HSO_(4)^(-) to H_(2)SO_(4)`
Promotional Banner

Topper's Solved these Questions

  • AROMATIC HYDROCARBONS

    AAKASH SERIES|Exercise Exercise 5.1.1|6 Videos
  • AROMATIC HYDROCARBONS

    AAKASH SERIES|Exercise Exercise 5.1.2|7 Videos
  • AROMATIC HYDROCARBONS

    AAKASH SERIES|Exercise PRACTICE EXERCISE|23 Videos
  • ALKALINE EARTH METALS

    AAKASH SERIES|Exercise ADDITIONAL PRACTICE EXERCISE ADDITIONAL QUESTIONS|15 Videos
  • ATOMIC STRUCTURE

    AAKASH SERIES|Exercise OBJECTIVE EXERCISE - 3 (RECENT AIPMT/NEET QUESTIONS)|20 Videos

Similar Questions

Explore conceptually related problems

Show that the role of conc. Sulphuric acid is not a dehydrating agent, but used for production of nitronium cation.

Sulphuric acid acts as dehydrating agent. Substantiate.

Sulphuric acid can be used as:

Sulphurous acid is a bleaching agent base on sodium. Explain.

(A) Formic acid is made poisonous with the presence of sulphuric acid (R ) Sulphuric acid acts as dehydrating agent liberating carbon monoxide from formic acid

During the reaction of alcohols with KI, why sulphuric acid is not used?

Why is sulphuric acid not used during the reaction of alcohols with KI ?

When 2-butanol is heated with an excess of concentrated sulphuric acid, the main product is

AAKASH SERIES-AROMATIC HYDROCARBONS-Problems
  1. Explain whether the compound is aromatic or not?

    Text Solution

    |

  2. Compare the number of hydrogen atoms per carbon atom of an arene with ...

    Text Solution

    |

  3. Why compounds like 1,3-cyclobutadiene, 1,3,5,7- cycloctatetrane and io...

    Text Solution

    |

  4. Which of the following compounds is more acidic?

    Text Solution

    |

  5. Write the sturcture and names of all possible isomers of trimethyl ben...

    Text Solution

    |

  6. What is the electrophile in chlorination of benzene with chlorine in p...

    Text Solution

    |

  7. Which is more acidic, acetylene or benzene?

    Text Solution

    |

  8. What are the ozonolysis products of ortho xylene?

    Text Solution

    |

  9. Show that the role of cone, sulphuric acid is not a dehydrating agent,...

    Text Solution

    |

  10. What happens when benzene reacts with n-propylchloride in presence of ...

    Text Solution

    |

  11. Compure acetylene and benzene with respect to the following: (a) hyb...

    Text Solution

    |

  12. What product is obtained when isobutyl chloride reacts with benzene in...

    Text Solution

    |

  13. Write the sequence of reactions to convert phenol into acetophenone.

    Text Solution

    |

  14. Which is more reactive, C(6)H(6) or C(6)D(6) towards electrophilic sub...

    Text Solution

    |

  15. What is the major product obtained by nitration of m-xylene?

    Text Solution

    |

  16. Predict the major product of chlorination of m-dinitrobenzene.

    Text Solution

    |

  17. Write the major product of the chlorination reaction of o-nitotoulene.

    Text Solution

    |

  18. . Where are X and Y?

    Text Solution

    |

  19. Is azulene polar and aromatic ?

    Text Solution

    |

  20. Why polynuclear aromatic compounds are toxic ?

    Text Solution

    |