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Equal moles of F(2(g)) and Cl(2(g)) are...

Equal moles of `F_(2(g)) and Cl_(2(g))` are introduced into a sealed container and heated to temperature T to attain the following equilibria. `Cl_(2(g)) + F_(2(g)) hArr 2C//F_((g)) , Kp_(I)= 3.2 , Cl_(2(g)) + 3 F_(2(g)) hArr 2 CIF_(2(g)) , Kp_(2) `. If partial pressures of CIF and `CIF_(3)` at equilibria are 0.2 and 0.04 atm respectively. What is the value of `Kp_(2)` ?

A

14.66 `atm^(-2)`

B

1.466 `atm^(-2)`

C

14.66 `atm^(-2)`

D

0.1466 `atm^(-2)`

Text Solution

Verified by Experts

The correct Answer is:
A


`:. 3.2=((0.2)^(2))/((P-0.12)(P-0.16)) implies P=0.2535` `:. 0.2535-0.12" "0.2535-0.16" "0.04`
`=0.1335" "=0.0935`
`Kp_(2)=((0.04)^(2))/((0.1335)(0.0952)^(3))=14.66 atm^(-2)`
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