Gradual warming of the almospbere due to trapping of radia1ion of long wavelength is called
Gradual warming of the almospbere due to trapping of radia1ion of long wavelength is called
A
air pollution
B
depletion of ozone layer
C
photo synthesis
D
green house effect
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The correct Answer is:
D
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Global warming of the atmosphere due to trapping of radiation of long wavelength is called
The observed wavelengths in the line spectrum of hydrogen atom were first expressed in terms of a series by Johann Jakob Balmer, a Swiss teacher. Balmer's empirical formula is (1)/(lambda) = R_(H)[(1)/(2^(2)) - (1)/(n^(2))] = n = 3, 4,5… R_(H) = 109678 cm^(-1) is the Rydberg constant. Niels Bohr derived this expression theoretically in 1913. The formula is a generalised to any on electron atom/ion. The wavelength of first line of Balmer spectrum of hydrogen will be :
The only electron in the hydrogen atom resides under ordinary conditions on the first orbit. When energy is supplied, the electron moves to higher energy orbit depending on the amount of energy absorbed. When this electron returns to any of the lower orbits, it emits energy. Lyman series is formed when the electron returns to the lowest orbit while Balmer series is formed when the electron returns to second orbit. Similarly, Paschen, Brackett and Pfund series are formed when electron returns to the third, fourth orbits from higher energy orbits respectively (as shown in figure) Maximum number of lines produced when an electron jumps from nth level to ground level is equal to (n(n-1))/(2) . For example, in the case of n = 4, number of lines produced is 6. (4 rarr 3, 4 rarr 2, 4 rarr 1, 3 rarr 2, 3 rarr 1, 2 rarr 1) . When an electron returns from n_(2) to n_(1) state, the number of lines in the spectrum will be equal to ((n_(2) - n_(1))(n_(2)-n_(1) +1))/(2) If the electron comes back from energy level having energy E_(2) to energy level having energy E_(2) then the difference may be expressed in terms of energy of photon as E_(2) - E_(1) = Delta E, lambda = (h c)/(Delta E) . Since h and c are constant, Delta E corresponds to definite energy, thus each transition from one energy level to another will prouce a higher of definite wavelength. THis is actually observed as a line in the spectrum of hydrogen atom. Wave number of the line is given by the formula bar(v) = RZ^(2)((1)/(n_(1)^(2)) - (1)/(n_(2)^(2))) Where R is a Rydberg constant (R = 1.1 xx 10^(7)) (i) First line of a series : it is called .line of logest wavelength. or .line of shortest energy.. (ii) Series limit of last of a series : It is the line of shortest wavelength or line of highest energy. In a single isolated atom in electron makes transition from 5^(th) excited state to 2^(nd) state the maximum number of different types of photons observed as
alpha - amino acids are high melting crystalline solids because of the zwitterion structure. They are moderately soluble in water. In acidic medium, alpha - amino acids exist as cations (I) and thus migrate towards cathode under the influence of an electric field. On the other hand, in alkaline medium, alpha - amino acids exist as anions (III) and thus migrate towards anode under the influence of an electric field. However, at some intermediate value of p^(H) , the concentration of the cationic form (I) and anionic form (III) will become equal and consequently the alpha - amino acid will exist primarily as the neutral dipolar ion (II). At this p^(H) , there would be no net migration of the amino acid in an electric field. This p^(H) at which there is no net migration of the amino acid under the influence of an applied electric field is called isoelectric point (pI). Each amino acid has a characteristic isoelectric point. The pH of an amino acid that does not have an ionisable side chain such as alanine isd average of pK_(a) values of the carboxyl group and the protonated amino group. H_(3)overset(+)(N)-overset("R")overset("|")("C")H-COOH overset(" "OH^(-)" ")underset(" "H^(+)" ")hArr H_(3)overset(+)(N)-underset("Zwitterion (II)")(overset("R")overset("|")("C")H)-COO^(-)overset(" "OH^(-)" ")underset(" "H^(+)" ")hArr underset((III))(overset(+)(N)-overset("R")overset("|")("C")H)-COO^(-) Further, the alpha - carbon of all the amino acids (except glycine) is chiral (asymmetric) and hence amino acids can exist in teo stereoisomeric forms i.e., D and L. However, all the nautrally occurring amino acids belong to the L - series. underset("L(-)Glyceraldehyde")(HO-overset("CHO ")overset("| ")underset(" "CH_(2)OH)underset("| ")("C ")-H)" " underset("L-Amino acid")(H_(2)N-overset("COOH")overset("| ")underset("R ")underset("| ")("C ")-H) In alanine, carboxyl group ionises at pK_(a1)=2.34 and ammonium ion at pK_(a2)=9.69 . The isoelectric point of the amino acid is at p^(H) .
The pressure developed in tracheary elements of xylem due to metabolic activity of roots 1s called:
f-block elements exhibit different oxidation state, colour, complex formation like properties. The size oflanthanides decreases due to poor screening effect of 4f electrons. It is called lanthanide contraction. Lanthanide hydroxides are basic in nature The colour of lanthanide ion is due to
Excited atoms emit radiations consisting of only certain discrete frequencies or wavelengths. In spectroscopy it is often more convenient to use frequencies or wave numbers than wavelength because frequencies and wave numbers are proportional to energy and spectroscopy involves transitions between different energy levels. The line spectrum shown by a mono electronic excited atom (a finger print of an atom) is called atomic spectrum. 1/(lambda) = Z^2 R [1/(n_1^2 - 1/(n_2^2)] The ratio of wavelength for II line of Balmer series and I line of Lyman series is
Excited atoms emit radiations consisting of only certain discrete frequencies or wavelengths. In spectroscopy it is often more convenient to use frequencies or wave numbers than wavelength because frequencies and wave numbers are proportional to energy and spectroscopy involves transitions between different energy levels. The line spectrum shown by a mono electronic excited atom (a finger print of an atom) is called atomic spectrum. 1/(lambda) = Z^2 R [1/(n_1^2 - 1/(n_2^2)] The given diagram indicates the energy levels of certain atom. When an electron moves from 2E level to E level, a photon of wavelength lambda is emitted. The wavelength of photon emitted during its transition from (4E)/(3) level to E level is
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