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A organic compound (P ) upon reacting wi...

A organic compound (P ) upon reacting with `NH_(3)` gives (Q). On heating, (Q) gives (R). (R) in presence of KOH reacts with `Br_(2)` to give ethylamine. (P) is :

A

`CH_(3)-underset(CH_(3))underset(|)(CH)-COOH`

B

`CH_(3)CH_(2)COOH`

C

`CH_(3)COOH`

D

`CH_(3)CH_(2)CH_(2)COOH`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to identify the organic compound (P) that reacts with ammonia (NH₃) to form compound (Q), which upon heating gives compound (R). Finally, (R) reacts with KOH and Br₂ to yield ethylamine. ### Step-by-Step Solution: 1. **Identify the Final Product (Ethylamine)**: - The final product we need to obtain is ethylamine (C₂H₅NH₂). 2. **Understanding the Reaction of (R) with KOH and Br₂**: - The reaction of an amide with KOH and Br₂ is known as the Hofmann degradation reaction. This reaction reduces the carbon chain of the amide by one carbon atom, yielding a primary amine. - Since we are getting ethylamine (C₂H₅NH₂) from (R), it implies that (R) must be an amide with three carbons (C₃H₇NO). 3. **Determine (R)**: - If (R) leads to ethylamine, we can deduce that (R) is propanamide (C₂H₅C(O)NH₂), which has three carbons. 4. **Relate (Q) to (R)**: - Since (R) is propanamide, we can see that (Q) must be the corresponding ammonium salt formed from the reaction of propanoic acid with ammonia. - Therefore, (Q) is propanamide (C₂H₅C(O)NH₂) formed by the reaction of propanoic acid with ammonia. 5. **Identify (P)**: - To find (P), we recognize that (P) must be the carboxylic acid that reacts with ammonia to form (Q). Since (Q) is propanamide, (P) must be propanoic acid (C₂H₅COOH). ### Conclusion: The organic compound (P) is propanoic acid (C₂H₅COOH).

To solve the problem, we need to identify the organic compound (P) that reacts with ammonia (NH₃) to form compound (Q), which upon heating gives compound (R). Finally, (R) reacts with KOH and Br₂ to yield ethylamine. ### Step-by-Step Solution: 1. **Identify the Final Product (Ethylamine)**: - The final product we need to obtain is ethylamine (C₂H₅NH₂). 2. **Understanding the Reaction of (R) with KOH and Br₂**: ...
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