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Which of the following is an inner orbit...

Which of the following is an inner orbital complex as well as diamagnetic in behaviour
[Atomic numbers Zn = 30, Cr = 24, Co = 27, Ni = 28.]

A

`[Zn(NH_(3))_(6)]^(2+)`

B

`[Ni(NH_(3))_(6)]^(2+)`

C

`[Cr(NH_(3))_(6)]^(3+)`

D

`[Co(NH_(3))_(6)]^(+)`

Text Solution

Verified by Experts

The correct Answer is:
D
`[Co(NH_(3))_(6)]^(3+)` is diamagnetic `(t_(2g)^(6) e g^(0))` and is inner orbital complex.
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