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Give the IUPAC names of the compounds. C...

Give the IUPAC names of the compounds. Classify them as alkyl, allylic, benzylic, vinylic and aryl halides and also as primary, secondary and tertiary halides.
` (i ) (CH_3)_3 C CH_2 CH (Cl) CH_3`
`(ii ) CH_3 CH_2 CH=CHCH_2 Cl,`
`(iii ) (CH_3)_2 CHCH_2 CH=C (Cl) CH_2 CH_3 and `
`(iv ) C_6 H_5 C (Cl ) CH_3)_2`

Text Solution

Verified by Experts

(i) `underset("2-Chloro-4, 4-dimethylpentante Alkyl halide (secondary)")(H_3overset(5)(C)-underset(CH_3)underset(|)overset(CH_3)overset(4|)(C)-overset(3)(C)H_2-underset(Cl)underset(|)overset(2)(C)H-overset(1)(C)H_3)`
(ii) `underset("1 -Chloropent - 2 - ene Allylic halide (primary)")(overset(5)(C)H_3overset(4)(C)H_2overset(3)(C)H=overset(2)(C)Hoverset(1)(C)H_2Cl)`
(iii) `underset("2-Chloro - 2 phenylpropane Benzylic halide (tertiary)")(C_6H_5-underset(CH_3)underset(|)overset(Cl)overset(|)(C)-CH_3)`
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Knowledge Check

  • IUPAC name of (CH_3)_2 CHCH_2 CH_2 Br is

    A
    1-Bromo-3-methylbutane
    B
    1-Bromo-3-methylpropane
    C
    1-Bromopentane
    D
    3-Bromopentane
  • The correct IUPAC name of CH_3 - CH_2 - CH (CH_3) - CH (C_2H_5)_2 is

    A
    4-Ethyl -3-methyl hexane
    B
    3-Ethyl-4-methyl hexane
    C
    4-Methyl-3-ethyl hexane
    D
    2,4, -Diethyl pentane
  • AAKASH SERIES-ALKYL AND ARYL HALIDES-EXAMPLES
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    7. A hydrocarbon ,C5 H(12) gives only one monochlorination product ....

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    8. Write the structures of all aromatic iodides with the formula C7 H7 I.

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    9. Write all the possible monochloro structural isomers that are formed o...

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    10. During the reaction of alcohols with KI, why sulphuric acid is not use...

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    11. Write the products of the following reactions : iii) CH3-CH2 -CH=...

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    12. Free radical bromination of n-butane yields 2-bromobutane as the major...

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    13. Give the structures of the major organic products from 3-ethyl-2-pente...

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    14. Among the three iso meric alkanes (C5H12), identify the one that on ch...

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    15. How is 1-iodobutane obtained from 1-butene?

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    16. Which isomer of C5 H(11) Cl has the highest boiling point and which h...

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    17. The observed rotation of 10ml of a solution containing 2g of a compoun...

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