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R-Cl is hydrolysed to R-OH slowly but th...

R-Cl is hydrolysed to R-OH slowly but the reaction is rapid in presence of KI as catalyst. Explain.

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KI supplies `l^(-)` ion which is strong nucleophile and hence reacts rapidly with R-Cl to form `R-I. I^(-)` is also a better leaving group than `Cl^(-)` . Hence R-I is hydrolysed rapidly to form R-OH and `I^(-).. I^(-)`  ion is again used in converting R-Cl to R-I.
`R-Cl + H_2O overset("slow)(rarr)R-OH+Cl^(-)`
`R-Cl + I^(-) underset(-Cl^(-))overset("fast")(rarr) R - I underset("fast")overset(+H_2O)(rarr)R-OH`
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AAKASH SERIES-ALKYL AND ARYL HALIDES-EXAMPLES
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  2. Why alkyl halides are not generally prepared in laboratory by free rad...

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  3. R-Cl is hydrolysed to R-OH slowly but the reaction is rapid in presenc...

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  4. Optically active 2-iodobutane on treatment with sodium iodide in aceto...

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  5. Expain the formation of the two products in the following reaction : ...

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  6. Why the chlorine atom in vinyl chloride is nonreactive?

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  7. Allyl iodide can be obtained from allyl chloride. Explain.

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  8. Predict the order of reactivity of the following compounds in SN1 and ...

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  9. Write the structures of major and minor products formed when 3-chloro-...

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  10. How do you distinguish between CH3CH = CHCl , CH3CH2Cl and CH2=CH-CH2C...

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  11. In the following pairs of halogen compounds, which would undergo SN2 r...

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  12. Predict the order of reactivity of the following compounds in SN1 and ...

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  13. Which alkyl halide from the following pairs would you expect to react ...

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  14. In the following pairs of halogen compounds, which compound undergoes ...

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  15. Identify A, B, C, D, E, R and R' in the following:

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  16. What is teflon ? How is it prepared ?

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  17. How will you distinguish between chloroform and carbon tetrachloride ?

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  18. How iodoform is distinguished from chloroform?

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  19. Among the three isomeric dichlorobenzenes , which has the highest...

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  20. Which product will form when optically active form of C4H9Br is subje...

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