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Nucleophilic substitution in aryl halide...

Nucleophilic substitution in aryl halides is facilitated by electron withdrawing groups while electrophilic substitution is facilitated by electron releasing groups. Why? 

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Nucleophilic substitution in aryl halides takes place via carbanion as intermediate, which are stabilised by electron withdrawing groups.
Electrophilic substitution takes place through carbocations as intermediates, which are stabilised by electron releasing groups. The rate of the reaction increases if the intermediate involved in this reaction is stabilised.
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The typical reaction of benzene and other aromatic compounds is electrophilic substitution. Presence of electron donating group activates the ring towards electrophilic substitution, while presence of electron withdrawing group deactivates the ring towards electrophilic substitution but at the same time activates the ring towards nucleophilic substitution. Some groups are predominantly meta directing and all of these are deactivating. Except halogen, most of the o- and p- directing groups are activating groups. (E.A.S = Electrophilic aromatic substation) Presence of nitro group in benzene ring:

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AAKASH SERIES-ALKYL AND ARYL HALIDES-EXAMPLES
  1. R-Cl is hydrolysed to R-OH slowly but the reaction is rapid in presenc...

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  2. Optically active 2-iodobutane on treatment with sodium iodide in aceto...

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  3. Expain the formation of the two products in the following reaction : ...

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  4. Why the chlorine atom in vinyl chloride is nonreactive?

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  5. Allyl iodide can be obtained from allyl chloride. Explain.

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  6. Predict the order of reactivity of the following compounds in SN1 and ...

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  7. Write the structures of major and minor products formed when 3-chloro-...

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  8. How do you distinguish between CH3CH = CHCl , CH3CH2Cl and CH2=CH-CH2C...

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  9. In the following pairs of halogen compounds, which would undergo SN2 r...

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  10. Predict the order of reactivity of the following compounds in SN1 and ...

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  11. Which alkyl halide from the following pairs would you expect to react ...

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  12. In the following pairs of halogen compounds, which compound undergoes ...

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  13. Identify A, B, C, D, E, R and R' in the following:

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  14. What is teflon ? How is it prepared ?

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  15. How will you distinguish between chloroform and carbon tetrachloride ?

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  16. How iodoform is distinguished from chloroform?

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  17. Among the three isomeric dichlorobenzenes , which has the highest...

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  18. Which product will form when optically active form of C4H9Br is subje...

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  19. Benzyl chloride undergoes nucleophilic substitution much more easily t...

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  20. Nucleophilic substitution in aryl halides is facilitated by electron w...

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