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The reaction of toulene with Cl2 in pres...

The reaction of toulene with `Cl_2` in presence of `FeCl_3` gives predominently 

A

m - Chloro toluene

B

Benzoyl chloride

C

Benzyl chloride

D

`o - & p - `Chloro toulenes

Text Solution

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The correct Answer is:
D
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The typical reaction of benzene and other aromatic compounds is electrophilic substitution. Presence of electron donating group activates the ring towards electrophilic substitution, while presence of electron withdrawing group deactivates the ring towards electrophilic substitution but at the same time activates the ring towards nucleophilic substitution. Some groups are predominantly meta directing and all of these are deactivating. Except halogen, most of the o- and p- directing groups are activating groups. (E.A.S = Electrophilic aromatic substation) The reaction of toluene with Cl_2 in presence of FeCl_3 gives predominantly:

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Knowledge Check

  • Ethyl benzene with Br_2 in the presence of FeBr_3 gives

    A
    Phenyl bromoethane
    B
    o and p-Bromotoluenes
    C
    o and p-Bromo ethyl benzenes
    D
    Mixture of all these

  • Ethyl benzene with Br_(2) in the presence of FeBr_(3) gives

    A
    Phenyl bromoethane
    B
    o and P-bromotoluenes
    C
    o and p-bromo ethyl benzenes
    D
    Mixture of all these

  • Ethyl benzene on reaction with bromine in presence of FeBr_3 , predominantly gives

    A
    B
    C
    D