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Write structures of prudlucts of the fol...

Write structures of prudlucts of the following reactions :
I) `CH_3CH=CH_2overset(H_2 O //H^(+))(rarr)`
II)
III) `CH_3-CH_2underset(CH_3)underset(|)(CH)-CHO`

Text Solution

Verified by Experts

I) `CH_3-CH(OH)-CH_3`
 II) `NaBH_4` can reduce aldehydes and ketones to the corresponding alcohols but it has no effect on ester group. Hence the product is

III) `CH_3-CH_2-underset(CH_3)underset(|)(CH)-CH_2OH`
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Write structure of the products of the CH_(3)-CH_(2)-underset(CH_(3))underset(|)CH-CHO overset(NaBH_(4))

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Give the major products that are formed by heating each ofthe following ethers with HI. i) CH_(3)-CH_(2)-overset(CH_(3))overset(|)CH-CH_(2)-O-CH_(2)-CH_(3) ii) CH_(3)-CH_(2)-CH_(2)-O-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-CH_(2)-CH_(3) iii)

Write the IUPAC name of CH_(3)-CH_(2)-underset(CH_(2)OH)underset(|)(CH)-CH_(2)-underset(CH_(2)CH_(3))underset(|)(CH)-CH_(3)

Write the structure of the major organic product in each of the following reactions: (i) CH_(3)CH_(2)CH_(2)Cl+NaIoverset("acetone")underset("heat")rarr (ii) (CH_(3))_(3)CBr+KOH overset("ethanol")underset("heat")rarr (iii) CH_(3)CH(Br)CH_(2)CH_(3)+NaOH overset("water")rarr (iv) CH_(3)CH_(2)Br+KCN overset("aq. ethanol")rarr (v) C_(6)H_(5)ONa+C_(2)H_(5)Clrarr (vi) CH_(3)CH_(2)CH=CH_(2)+HBr overset("peroxide")rarr (viii) CH_(3)CH=C(CH_(3))_(2)+HBr rarr

What is the name of the following reaction ? CH_3CH_2CH_2Br underset("dry acetone")overset(NaI)(rarr)CH_3CH_2CH_2I .

Write the IUPAC name of the CH_(3)-O-CH_(2)-underset(CH_(3))underset(|)CH-CH_(3) compound.

AAKASH SERIES-ALCOHOLS, PHENOLS AND ETHERS-EXAMPLES
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  2. Give the structures and IUPAC names of the products expected from the ...

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  3. Write structures of prudlucts of the following reactions : I) CH3CH=...

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  4. Show how are the following alcohols are prepared by the reaction of a ...

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  5. Arrange the following sets of compounds in order of their increasing b...

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  6. Write the aromatic structures of all isomers with the formula C7H8O.

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  7. What is the tautomer of phenol ? Which is more stable ?

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  8. How is salicylic acid converted to phenol?

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  9. Explain the method of preparation of resorcinol from benzene.

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  10. Phenol decolourises reddish brown colour of bromine, though it is not ...

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  11. Write the decreasing order of acidic strengths of the following: A :...

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  12. Write the electrophile and intermediate in Reimer-Tiemann reaction.

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  13. What is the reason for the formation of tribromo phenol when phenol is...

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  14. Phenol is treated with C Cl(4) in presence of NaOH. What happens ?

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  15. Write the structures of the major products expected from the following...

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  16. Dehydration of alcohols is suitable for preparing ethers having primar...

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  17. Give one example of an ether which cannot be decomposed by HI.

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  18. Ether can be dried over sodium, but not alcohol. Why?

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  19. Chloroethane, 2-chloropropane and chloroethene are treated with methox...

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  20. Diphenyl ether cannot cleaved by treatment HI. Why?

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