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Hyper conjugation involves overlap of th...

Hyper conjugation involves overlap of the following orbitals

A

`sigma-sigma`

B

`sigma-p`

C

`p-p`

D

`pi-pi`

Text Solution

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The correct Answer is:
B
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Hyper conjugation phenomenon is possible in:

The central metal ion in the complex makes available a number of empty orbitals for the formation of co-ordinate bonds with suitable ligands. The inner d-orbitals or outer d-orbitals are involved. The empty hybrid orbitals of metal ion overlap with the filled orbitals of ligand to from metal ligand co-ordinate bonds. For co-ordination number 6 octahedral geometry and sp^(3),d^(2)ord^(2)sp^(2) hybridisation involved and for cordiantion number 4 tetrahedral geometry, square planar geometry and sp^(3).dsp^(2) hybridisation involved. Type of complex formed in [Fe(H_(2)O)_(6)]^(+3) ion

The central metal ion in the complex makes available a number of empty orbitals for the formation of co-ordinate bonds with suitable ligands. The inner d-orbitals or outer d-orbitals are involved. The empty hybrid orbitals of metal ion overlap with the filled orbitals of ligand to from metal ligand co-ordinate bonds. For co-ordination number 6 octahedral geometry and sp^(3),d^(2)ord^(2)sp^(2) hybridisation involved and for cordiantion number 4 tetrahedral geometry, square planar geometry and sp^(3).dsp^(2) hybridisation involved. Hybridisation present in [Cr(NH_(3))_(6)]^(+3)

The central metal ion in the complex makes available a number of empty orbitals for the formation of co-ordinate bonds with suitable ligands. The inner d-orbitals or outer d-orbitals are involved. The empty hybrid orbitals of metal ion overlap with the filled orbitals of ligand to from metal ligand co-ordinate bonds. For co-ordination number 6 octahedral geometry and sp^(3),d^(2)ord^(2)sp^(2) hybridisation involved and for cordiantion number 4 tetrahedral geometry, square planar geometry and sp^(3).dsp^(2) hybridisation involved. Geometry of [Ni(CN)_(4)]^(-2) ion is