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Three moles of oxygen ar mixed with two ...

Three moles of oxygen ar mixed with two moles of helium. What will be the ratio of specific heats at constant pressure and constant volume for the mixture ?

A

`2.5`

B

`3.5`

C

`1.5`

D

1

Text Solution

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The correct Answer is:
To find the ratio of specific heats at constant pressure (Cp) and constant volume (Cv) for a mixture of gases, we can follow these steps: ### Step 1: Identify the gases and their moles We have: - Oxygen (O2): 3 moles - Helium (He): 2 moles ### Step 2: Determine the specific heats for each gas 1. **For Oxygen (O2)**: - Cv (O2) = \( \frac{5}{2} R \) - Cp (O2) = \( \frac{7}{2} R \) The ratio of specific heats (γ) for oxygen: \[ \gamma_1 = \frac{C_p}{C_v} = \frac{\frac{7}{2} R}{\frac{5}{2} R} = \frac{7}{5} \] 2. **For Helium (He)**: - Cv (He) = \( \frac{3}{2} R \) - Cp (He) = \( \frac{5}{2} R \) The ratio of specific heats (γ) for helium: \[ \gamma_2 = \frac{C_p}{C_v} = \frac{\frac{5}{2} R}{\frac{3}{2} R} = \frac{5}{3} \] ### Step 3: Calculate the effective specific heat ratio for the mixture Using the formula for the effective specific heat ratio (γ_net) for a mixture: \[ \gamma_{net} = \frac{n_1 \gamma_1 + n_2 \gamma_2}{n_1 + n_2} \] where: - \( n_1 = 3 \) (moles of O2) - \( n_2 = 2 \) (moles of He) Substituting the values: \[ \gamma_{net} = \frac{3 \cdot \frac{7}{5} + 2 \cdot \frac{5}{3}}{3 + 2} \] ### Step 4: Simplify the expression Calculating the numerator: \[ 3 \cdot \frac{7}{5} = \frac{21}{5} \] \[ 2 \cdot \frac{5}{3} = \frac{10}{3} \] Finding a common denominator (15): \[ \frac{21}{5} = \frac{63}{15} \] \[ \frac{10}{3} = \frac{50}{15} \] Adding these: \[ \frac{63}{15} + \frac{50}{15} = \frac{113}{15} \] Now, the denominator: \[ 3 + 2 = 5 \] So: \[ \gamma_{net} = \frac{\frac{113}{15}}{5} = \frac{113}{75} \] ### Step 5: Final calculation Calculating: \[ \gamma_{net} = \frac{113}{75} \approx 1.51 \] ### Conclusion The ratio of specific heats at constant pressure and constant volume for the mixture is approximately \( 1.51 \).

To find the ratio of specific heats at constant pressure (Cp) and constant volume (Cv) for a mixture of gases, we can follow these steps: ### Step 1: Identify the gases and their moles We have: - Oxygen (O2): 3 moles - Helium (He): 2 moles ### Step 2: Determine the specific heats for each gas ...
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