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Two identical containers A and B with fr...

Two identical containers A and B with frictionless pistons contain the same ideal gas at the same temperature and the same velocity V. The mass of the gas in A is `m_A,` and that in B is `m_B`. The gas in each cylinder is now allowed to expand isothermally to the same final volume 2V. The changes in the pressure in A and B are found to be `DeltaP and 1.5 DeltaP` respectively. Then

A

`4m_A = 9m_B`

B

`3m_A = 3m_B`

C

`3m_A = 2m_B`

D

`9m_A = 4m_B`

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The correct Answer is:
To solve the problem, we need to analyze the situation involving two identical containers A and B containing the same ideal gas. Let's break down the steps to find the relationship between the masses of the gases in the two containers. ### Step 1: Understand the Initial Conditions Both containers A and B contain the same ideal gas at the same temperature and velocity. The masses of the gases in containers A and B are denoted as \( m_A \) and \( m_B \), respectively. ### Step 2: Write the Initial Pressure Equations The pressure of an ideal gas can be expressed using the ideal gas law: \[ P = \frac{nRT}{V} \] where: - \( n \) is the number of moles, - \( R \) is the gas constant, - \( T \) is the temperature, - \( V \) is the volume. Since the number of moles \( n \) can be expressed as \( n = \frac{m}{M} \) (where \( m \) is the mass of the gas and \( M \) is the molar mass), we can write the initial pressures for both containers: For container A: \[ P_A = \frac{m_A RT}{MV} \] For container B: \[ P_B = \frac{m_B RT}{MV} \] ### Step 3: Write the Final Pressure Equations After Isothermal Expansion After the gases expand isothermally to a final volume of \( 2V \), the pressures become: For container A: \[ P_A' = \frac{m_A RT}{M(2V)} = \frac{m_A RT}{2MV} \] For container B: \[ P_B' = \frac{m_B RT}{M(2V)} = \frac{m_B RT}{2MV} \] ### Step 4: Calculate the Change in Pressure for Both Containers The change in pressure for container A is: \[ \Delta P_A = P_A - P_A' = \frac{m_A RT}{MV} - \frac{m_A RT}{2MV} = \frac{m_A RT}{MV} - \frac{m_A RT}{2MV} = \frac{m_A RT}{2MV} \] The change in pressure for container B is: \[ \Delta P_B = P_B - P_B' = \frac{m_B RT}{MV} - \frac{m_B RT}{2MV} = \frac{m_B RT}{MV} - \frac{m_B RT}{2MV} = \frac{m_B RT}{2MV} \] ### Step 5: Relate the Changes in Pressure According to the problem, we have: \[ \Delta P_A = \Delta P \quad \text{and} \quad \Delta P_B = 1.5 \Delta P \] Substituting the expressions for \( \Delta P_A \) and \( \Delta P_B \): \[ \frac{m_A RT}{2MV} = \Delta P \quad \text{(1)} \] \[ \frac{m_B RT}{2MV} = 1.5 \Delta P \quad \text{(2)} \] ### Step 6: Substitute Equation (1) into Equation (2) From equation (1), we can express \( \Delta P \): \[ \Delta P = \frac{m_A RT}{2MV} \] Substituting this into equation (2): \[ \frac{m_B RT}{2MV} = 1.5 \left(\frac{m_A RT}{2MV}\right) \] ### Step 7: Simplify the Equation Cancelling \( RT/2MV \) from both sides gives: \[ m_B = 1.5 m_A \] ### Step 8: Express the Relationship Between \( m_A \) and \( m_B \) Rearranging gives: \[ m_A = \frac{2}{3} m_B \] ### Conclusion Thus, the relationship between the masses of the gases in the two containers is: \[ 3m_A = 2m_B \]
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