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Molar conductivity of 0.15 M solution of...

Molar conductivity of 0.15 M solution of KCI at 298 K, if its conductivity is 0.0152 S `cm^(-1)` will be

A

`124 Omega^(-1) "cm"^(2) "mol"^(-1)`

B

`204 Omega^(-1) "cm"^(2) "mol"^(-1)`

C

`101 Omega^(-1) "cm"^(2) "mol"^(-1)`

D

`300 Omega^(-1) "cm"^(2) "mol"^(-1)`

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The correct Answer is:
To find the molar conductivity (Λm) of a 0.15 M solution of KCl at 298 K given its conductivity (κ) of 0.0152 S cm⁻¹, we can use the formula: \[ \Lambda_m = \frac{\kappa \times 1000}{C} \] Where: - \( \Lambda_m \) = molar conductivity in S cm² mol⁻¹ - \( \kappa \) = conductivity in S cm⁻¹ - \( C \) = concentration in mol L⁻¹ (M) ### Step-by-Step Solution: 1. **Identify the given values**: - Conductivity (κ) = 0.0152 S cm⁻¹ - Concentration (C) = 0.15 M 2. **Convert the concentration to the appropriate units**: - Since the concentration is already in mol L⁻¹, we can use it directly. 3. **Substitute the values into the formula**: \[ \Lambda_m = \frac{0.0152 \, \text{S cm}^{-1} \times 1000}{0.15 \, \text{mol L}^{-1}} \] 4. **Calculate the numerator**: \[ 0.0152 \times 1000 = 15.2 \, \text{S cm}^{-1} \] 5. **Now divide by the concentration**: \[ \Lambda_m = \frac{15.2 \, \text{S cm}^{-1}}{0.15 \, \text{mol L}^{-1}} = 101.33 \, \text{S cm}^2 \text{mol}^{-1} \] 6. **Round off the answer**: - The molar conductivity of the solution is approximately \( 101.33 \, \text{S cm}^2 \text{mol}^{-1} \). ### Final Answer: \[ \Lambda_m \approx 101.33 \, \text{S cm}^2 \text{mol}^{-1} \]

To find the molar conductivity (Λm) of a 0.15 M solution of KCl at 298 K given its conductivity (κ) of 0.0152 S cm⁻¹, we can use the formula: \[ \Lambda_m = \frac{\kappa \times 1000}{C} \] Where: - \( \Lambda_m \) = molar conductivity in S cm² mol⁻¹ ...
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