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When during electrolusis of a solution o...

When during electrolusis of a solution of `AgNO_3, 9650` coulmbs of charge pass through the electroplationg bath, the mass of silver deposited on the cathode will be:

A

108 g

B

10.8 g

C

1.08 g

D

216 g

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The correct Answer is:
To find the mass of silver deposited on the cathode during the electrolysis of a solution of silver nitrate when 9650 coulombs of charge pass through, we can use Faraday's laws of electrolysis. Here's the step-by-step solution: ### Step 1: Understand the Formula According to Faraday's first law of electrolysis, the mass (W) of a substance deposited at an electrode is directly proportional to the quantity of electricity (Q) that passes through the electrolyte. The formula is given by: \[ W = Z \cdot Q \] where \( Z \) is the electrochemical equivalent of the substance. ### Step 2: Determine the Electrochemical Equivalent (Z) From Faraday's second law, we know: \[ Z = \frac{E}{F} \] where: - \( E \) is the equivalent weight of the substance (for silver, \( E = 108 \, \text{g} \)), - \( F \) is Faraday's constant, which is approximately \( 96500 \, \text{C/mol} \). ### Step 3: Substitute Values to Find Z Now we can substitute the values into the equation for \( Z \): \[ Z = \frac{108 \, \text{g}}{96500 \, \text{C/mol}} \] ### Step 4: Calculate Z Calculating \( Z \): \[ Z = \frac{108}{96500} \approx 0.00112 \, \text{g/C} \] ### Step 5: Use the Charge to Find Mass (W) Now, we can substitute \( Z \) back into the first law of electrolysis: \[ W = Z \cdot Q \] Substituting the values: \[ W = 0.00112 \, \text{g/C} \cdot 9650 \, \text{C} \] ### Step 6: Calculate W Calculating \( W \): \[ W = 0.00112 \cdot 9650 \approx 10.8 \, \text{g} \] ### Conclusion The mass of silver deposited on the cathode will be **10.8 g**.

To find the mass of silver deposited on the cathode during the electrolysis of a solution of silver nitrate when 9650 coulombs of charge pass through, we can use Faraday's laws of electrolysis. Here's the step-by-step solution: ### Step 1: Understand the Formula According to Faraday's first law of electrolysis, the mass (W) of a substance deposited at an electrode is directly proportional to the quantity of electricity (Q) that passes through the electrolyte. The formula is given by: \[ W = Z \cdot Q \] where \( Z \) is the electrochemical equivalent of the substance. ### Step 2: Determine the Electrochemical Equivalent (Z) ...
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