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Electrode potential for Mg electrode var...

Electrode potential for `Mg` electrode varies according to the equation
`E_(Mg^(2+)|Mg)=E_(Mg^(2+)|Mg)^(ϴ) -(0.059)/2 "log" 1/([Mg^(2+)])`
The graph of `E_(Mg^(2+)|Mg) vs log [Mg^(2+)]` is

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The correct Answer is:
To solve the problem, we need to analyze the given equation for the electrode potential of the magnesium electrode and determine the nature of the graph of \( E_{Mg^{2+}|Mg} \) versus \( \log [Mg^{2+}] \). ### Step-by-Step Solution: 1. **Understanding the Nernst Equation**: The Nernst equation for the magnesium electrode is given as: \[ E_{Mg^{2+}|Mg} = E_{Mg^{2+}|Mg}^{\circ} - \frac{0.059}{2} \log \left( \frac{1}{[Mg^{2+}]} \right) \] This can be rewritten as: \[ E_{Mg^{2+}|Mg} = E_{Mg^{2+}|Mg}^{\circ} + \frac{0.059}{2} \log [Mg^{2+}] \] 2. **Identifying the Variables**: In this equation, we can identify: - \( E \) (the electrode potential) corresponds to \( E_{Mg^{2+}|Mg} \) - \( \log [Mg^{2+}] \) is the independent variable (let's denote it as \( x \)) - The slope \( m \) of the line is \( \frac{0.059}{2} \) - The y-intercept \( c \) is \( E_{Mg^{2+}|Mg}^{\circ} \) 3. **Formulating the Linear Equation**: The equation can be expressed in the form of a linear equation \( y = mx + c \): \[ E = \frac{0.059}{2} \log [Mg^{2+}] + E_{Mg^{2+}|Mg}^{\circ} \] Here, \( y \) is \( E \), \( m \) is \( \frac{0.059}{2} \), \( x \) is \( \log [Mg^{2+}] \), and \( c \) is \( E_{Mg^{2+}|Mg}^{\circ} \). 4. **Graph Characteristics**: - The graph of \( E \) versus \( \log [Mg^{2+}] \) will be a straight line. - The slope of the line is positive since \( \frac{0.059}{2} \) is a positive value. - The y-intercept will be at \( E_{Mg^{2+}|Mg}^{\circ} \). 5. **Conclusion**: Therefore, the graph of \( E_{Mg^{2+}|Mg} \) versus \( \log [Mg^{2+}] \) is a straight line with a positive slope.

To solve the problem, we need to analyze the given equation for the electrode potential of the magnesium electrode and determine the nature of the graph of \( E_{Mg^{2+}|Mg} \) versus \( \log [Mg^{2+}] \). ### Step-by-Step Solution: 1. **Understanding the Nernst Equation**: The Nernst equation for the magnesium electrode is given as: \[ E_{Mg^{2+}|Mg} = E_{Mg^{2+}|Mg}^{\circ} - \frac{0.059}{2} \log \left( \frac{1}{[Mg^{2+}]} \right) ...
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