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Which of the following statement is corr...

Which of the following statement is correct?

A

`E_"cell"` and `Delta_rG` of cell reaction both are extensive properties.

B

`E_"cell"` and `Delta_rG` of cell reaction both are intensive properties.

C

`E_"cell"` is an intensive property while `Delta_rG` of cell reaction is an extensive property.

D

`E_"cell"` is an intensive property while `Delta_rG` of cell reaction is an intensive property.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding which statement is correct, we will analyze the concepts of intensive and extensive properties, as well as the relationship between ΔG (Gibbs free energy) and E_cell (electrode potential). ### Step-by-Step Solution: 1. **Understanding Intensive and Extensive Properties:** - **Intensive Property:** An intensive property is a physical property that does not depend on the size or amount of material in the system. Examples include temperature, pressure, and density. - **Extensive Property:** An extensive property is a physical property that does depend on the size or amount of material in the system. Examples include mass, volume, and total energy. 2. **Identifying ΔG and E_cell:** - **ΔG (Gibbs Free Energy):** The change in Gibbs free energy is an extensive property. It is calculated using the formula: \[ ΔG = -nFE_{cell} \] where \( n \) is the number of moles of electrons transferred, \( F \) is Faraday's constant, and \( E_{cell} \) is the cell potential. - **E_cell (Electrode Potential):** The electrode potential is an intensive property. It does not change with the amount of material present in the system. 3. **Analyzing the Options:** - Based on the definitions and relationships established, we can conclude: - E_cell is an intensive property. - ΔG is an extensive property. 4. **Selecting the Correct Statement:** - From the analysis, we find that the correct statement among the options provided is that E_cell is an intensive property and ΔG is an extensive property. Therefore, the correct answer is **Option C**. ### Final Answer: The correct statement is **Option C**: E_cell is an intensive property, while ΔG is an extensive property.
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