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While charging the lead storage battery:...

While charging the lead storage battery:

A

`PbSO_4` anode is reduced to Pb

B

`PbSO_4` cathode is reduced to Pb

C

`PbSO_4` cathode is oxidised to Pb

D

`PbSO_4` anode is oxidised to `PbO_2`

Text Solution

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The correct Answer is:
To solve the question regarding the charging of a lead storage battery, we will analyze the reactions occurring at the anode and cathode during the charging process. ### Step-by-Step Solution: 1. **Identify the Components of the Lead Storage Battery:** - The lead storage battery consists of lead (Pb) as the anode and lead dioxide (PbO2) as the cathode. The electrolyte is typically a sulfuric acid solution (H2SO4). 2. **Understand the Charging Process:** - During the charging process, electrical energy is supplied to the battery, reversing the chemical reactions that occur during discharge. 3. **Anode Reaction:** - At the anode (negative plate), lead sulfate (PbSO4) is converted back to lead (Pb). The reaction can be represented as: \[ \text{PbSO}_4 + 2e^- + 2H^+ \rightarrow \text{Pb} + \text{H}_2\text{SO}_4 \] - Here, lead sulfate is reduced to lead, and hydrogen ions are produced. 4. **Cathode Reaction:** - At the cathode (positive plate), lead sulfate (PbSO4) is converted back to lead dioxide (PbO2). The reaction can be represented as: \[ \text{PbSO}_4 + 2e^- \rightarrow \text{PbO}_2 + \text{H}_2\text{SO}_4 \] - In this reaction, lead sulfate is oxidized to lead dioxide. 5. **Overall Reaction:** - The overall reaction during the charging of the lead storage battery can be summarized as: \[ 2\text{PbSO}_4 + 2H_2O \rightarrow 2\text{Pb} + \text{PbO}_2 + 2\text{H}_2\text{SO}_4 \] - This shows the conversion of lead sulfate back to lead and lead dioxide, with the regeneration of sulfuric acid. 6. **Conclusion:** - Thus, during the charging of a lead storage battery, lead sulfate is reduced to lead at the anode, while at the cathode, lead sulfate is oxidized to lead dioxide.

To solve the question regarding the charging of a lead storage battery, we will analyze the reactions occurring at the anode and cathode during the charging process. ### Step-by-Step Solution: 1. **Identify the Components of the Lead Storage Battery:** - The lead storage battery consists of lead (Pb) as the anode and lead dioxide (PbO2) as the cathode. The electrolyte is typically a sulfuric acid solution (H2SO4). 2. **Understand the Charging Process:** ...
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