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For a chemical reaction A rarr B, the ra...

For a chemical reaction `A rarr B`, the rate of reaction increases by a factor of `1.837` when the concentration of `A` is increased by `1.5` time. The order of reaction with respect to `A` is:

A

1

B

1.5

C

2

D

2.5

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The correct Answer is:
To determine the order of the reaction with respect to A for the reaction \( A \rightarrow B \), we can follow these steps: ### Step 1: Write the rate law expression For the reaction \( A \rightarrow B \), the rate of the reaction can be expressed as: \[ r = k [A]^n \] where: - \( r \) is the rate of the reaction, - \( k \) is the rate constant, - \( [A] \) is the concentration of reactant A, - \( n \) is the order of the reaction with respect to A. ### Step 2: Set up the initial and changed conditions Let the initial concentration of A be \( [A] \) and the initial rate be \( r \). When the concentration of A is increased by 1.5 times, the new concentration becomes: \[ [A]' = 1.5 [A] \] The new rate of reaction becomes: \[ r' = k [A']^n = k (1.5 [A])^n = k (1.5^n) [A]^n \] ### Step 3: Relate the rates before and after the change According to the problem, the rate increases by a factor of 1.837: \[ r' = 1.837 r \] Substituting the expressions for \( r' \) and \( r \): \[ k (1.5^n) [A]^n = 1.837 (k [A]^n) \] ### Step 4: Cancel out common terms Since \( k \) and \( [A]^n \) are common on both sides, we can simplify: \[ 1.5^n = 1.837 \] ### Step 5: Take logarithms Taking the logarithm of both sides gives: \[ \log(1.5^n) = \log(1.837) \] Using the property of logarithms, we can rewrite this as: \[ n \log(1.5) = \log(1.837) \] ### Step 6: Solve for \( n \) Now, we can solve for \( n \): \[ n = \frac{\log(1.837)}{\log(1.5)} \] ### Step 7: Calculate the logarithms Using a calculator: - \( \log(1.837) \approx 0.2641 \) - \( \log(1.5) \approx 0.1761 \) Substituting these values into the equation: \[ n = \frac{0.2641}{0.1761} \approx 1.5 \] ### Conclusion The order of the reaction with respect to A is: \[ \boxed{1.5} \]

To determine the order of the reaction with respect to A for the reaction \( A \rightarrow B \), we can follow these steps: ### Step 1: Write the rate law expression For the reaction \( A \rightarrow B \), the rate of the reaction can be expressed as: \[ r = k [A]^n \] where: ...
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