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For a reaction AtoB, the rate of reactio...

For a reaction A`to`B, the rate of reaction becomes twenty seven times when the concentration of A is increased three times. What is the order of the reaction?

A

2

B

1

C

3

D

0

Text Solution

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The correct Answer is:
To determine the order of the reaction A → B based on the information provided, we can follow these steps: ### Step 1: Understand the relationship between rate and concentration The rate of a reaction can be expressed as: \[ R = k[A]^n \] where: - \( R \) is the rate of the reaction, - \( k \) is the rate constant, - \( [A] \) is the concentration of reactant A, - \( n \) is the order of the reaction. ### Step 2: Set up the initial and new conditions According to the problem, when the concentration of A is increased three times, the rate of the reaction becomes 27 times the original rate. We can denote: - Original concentration of A as \( [A] \) - New concentration of A as \( 3[A] \) - Original rate as \( R \) - New rate as \( R' = 27R \) ### Step 3: Write the equations for the original and new rates Using the rate equation for both conditions: 1. Original rate: \[ R = k[A]^n \] 2. New rate: \[ R' = k(3[A])^n = k \cdot 3^n \cdot [A]^n \] ### Step 4: Relate the two rates Since \( R' = 27R \), we can substitute the expressions for \( R \) and \( R' \): \[ k \cdot 3^n \cdot [A]^n = 27 \cdot k[A]^n \] ### Step 5: Cancel out common terms We can cancel \( k \) and \( [A]^n \) from both sides (assuming \( [A] \neq 0 \)): \[ 3^n = 27 \] ### Step 6: Express 27 as a power of 3 We know that: \[ 27 = 3^3 \] Thus, we can rewrite the equation as: \[ 3^n = 3^3 \] ### Step 7: Equate the exponents Since the bases are the same, we can equate the exponents: \[ n = 3 \] ### Conclusion The order of the reaction is \( n = 3 \). ### Final Answer The order of the reaction is **3**. ---

To determine the order of the reaction A → B based on the information provided, we can follow these steps: ### Step 1: Understand the relationship between rate and concentration The rate of a reaction can be expressed as: \[ R = k[A]^n \] where: - \( R \) is the rate of the reaction, - \( k \) is the rate constant, ...
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