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The temperature dependence of the rate o...

The temperature dependence of the rate of a chemical reaction can be explained by Arrhenius equaiton which is

A

`k = Ae^(Ea//RT)`

B

`k = Ae^(-Ea//RT)`

C

`k = Ae xx (E_(a))/(RT)`

D

`k = Ae xx (RT)/(E_(a))`

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The correct Answer is:
To solve the question regarding the temperature dependence of the rate of a chemical reaction as explained by the Arrhenius equation, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Arrhenius Equation**: The Arrhenius equation describes how the rate constant (k) of a reaction depends on temperature (T) and activation energy (Ea). It is mathematically represented as: \[ k = A e^{-\frac{E_a}{RT}} \] where: - \( k \) = rate constant - \( A \) = pre-exponential factor (frequency factor) - \( E_a \) = activation energy (in joules per mole) - \( R \) = universal gas constant (8.314 J/(mol·K)) - \( T \) = temperature (in Kelvin) 2. **Identify the Components**: In the equation: - The term \( A \) represents the frequency of collisions and the orientation of reactants. - The exponential term \( e^{-\frac{E_a}{RT}} \) indicates how the rate constant decreases with increasing activation energy and how it increases with temperature. 3. **Analyze Temperature Dependence**: - As temperature (T) increases, the term \( \frac{E_a}{RT} \) decreases, leading to an increase in the value of \( k \). - This means that higher temperatures generally lead to faster reaction rates, as more molecules have sufficient energy to overcome the activation energy barrier. 4. **Conclusion**: The Arrhenius equation effectively shows that the rate of a chemical reaction increases with an increase in temperature due to the exponential relationship between temperature and the activation energy. ### Final Answer: The Arrhenius equation that explains the temperature dependence of the rate of a chemical reaction is: \[ k = A e^{-\frac{E_a}{RT}} \]
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