Home
Class 12
CHEMISTRY
The temperature dependence of the rate o...

The temperature dependence of the rate of a chemical reaction is given by arrhenius equation, `k = Ae^(-Ea//RT)`. Which of the following graphs will be a striaght line?

A

In A vs 1/T

B

In A vs `E_(a)`

C

In K vs 1/T

D

In k vs `-E_(a) //R`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which graph will be a straight line based on the Arrhenius equation, we can follow these steps: ### Step 1: Write down the Arrhenius equation The Arrhenius equation is given by: \[ k = A e^{-\frac{E_a}{RT}} \] where: - \( k \) is the rate constant, - \( A \) is the pre-exponential factor, - \( E_a \) is the activation energy, - \( R \) is the universal gas constant, and - \( T \) is the temperature in Kelvin. ### Step 2: Take the natural logarithm of both sides Taking the natural logarithm of the Arrhenius equation gives us: \[ \ln k = \ln A - \frac{E_a}{RT} \] ### Step 3: Rearrange the equation Rearranging the equation, we can express it in the form of \( y = mx + c \): \[ \ln k = -\frac{E_a}{R} \cdot \frac{1}{T} + \ln A \] ### Step 4: Identify the components of the linear equation From the rearranged equation: - The slope \( m \) is \( -\frac{E_a}{R} \) - The y-intercept \( c \) is \( \ln A \) ### Step 5: Determine the graph that represents a straight line The equation \( \ln k = -\frac{E_a}{R} \cdot \frac{1}{T} + \ln A \) indicates that if we plot \( \ln k \) (y-axis) against \( \frac{1}{T} \) (x-axis), we will obtain a straight line. ### Conclusion Thus, the graph that will be a straight line is: **Option C: \( \ln k \) versus \( \frac{1}{T} \)**. ---

To determine which graph will be a straight line based on the Arrhenius equation, we can follow these steps: ### Step 1: Write down the Arrhenius equation The Arrhenius equation is given by: \[ k = A e^{-\frac{E_a}{RT}} \] where: - \( k \) is the rate constant, - \( A \) is the pre-exponential factor, ...
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    NCERT FINGERTIPS ENGLISH|Exercise Higher Order Thinking Skills|9 Videos
  • CHEMICAL KINETICS

    NCERT FINGERTIPS ENGLISH|Exercise NCERT EXEMPLAR PROBLEMS|17 Videos
  • BIOMOLECULES

    NCERT FINGERTIPS ENGLISH|Exercise Assertion And Reason|15 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    NCERT FINGERTIPS ENGLISH|Exercise NCERT Exemplar|15 Videos

Similar Questions

Explore conceptually related problems

The temperature dependence of the rate of a chemical reaction can be explained by Arrhenius equaiton which is

In Arrhenius equation , K=Ae^(-E_a//RT) . The A is

The temperature dependence of rate constant (k) of a chemical reaction is written in terms of Arrhenius equation, k=Ae^(-E_(a)//RT)) Activation energy (E_(a)) of the reaction can be calculate by plotting

In the Arrhenius equation: k = A exp(-E_(a)//RT) , the rate constant

If the rate expression for a chemical reaction is given by Rate = K[A]^n[B]^m then

Rate of a reaction can be expressed by Arrhenius equation as: k = Ae^(-E_(a)//RT) In this equation, E_(a) represents:

Which curve corresponds to the temperature dependance of the rate R of a simple one step reaction ?

NCERT FINGERTIPS ENGLISH-CHEMICAL KINETICS-Assertion And Reason
  1. The temperature dependence of the rate of a chemical reaction is given...

    Text Solution

    |

  2. Assertion : Precipitation of silver chloride occurs instantaneously by...

    Text Solution

    |

  3. Assertion : The rate of reaction is the rate of change of concentratio...

    Text Solution

    |

  4. Assertion : For the reaction CHCI(3) + CI(2) to CCI(4) HCI Rate = ...

    Text Solution

    |

  5. Assertion : Order of a reaction with respect to any reactant can be ze...

    Text Solution

    |

  6. Assertion : Molecularity greater than three is not observed. Reason ...

    Text Solution

    |

  7. Assertion : Complex reaction takes place in different steps and the sl...

    Text Solution

    |

  8. Assertion : The decomposition of gaseous ammonia on a hot platinum sur...

    Text Solution

    |

  9. Assertion : For a first order reaction,t(1//2) is indepent of rate con...

    Text Solution

    |

  10. Assertion : The reaction underset("Cane sugar")(C(12)H(22)O(11)) + H...

    Text Solution

    |

  11. Assertion : The rate of a reaction sometimes does not depend on concen...

    Text Solution

    |

  12. Assertion : For a chemical reaction with rise in temperature by 10^(@)...

    Text Solution

    |

  13. Assertion : E(a) of the forward reaction is higher than that of backwa...

    Text Solution

    |

  14. Assertion : A catalyst increases the rate of reaction without itself u...

    Text Solution

    |

  15. Assertion : All molecules collisions lead to the formation of products...

    Text Solution

    |

  16. Assertion : Rate of reaction increases with increase in temperature. ...

    Text Solution

    |