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The rate of certain hypothetical reactio...

The rate of certain hypothetical reaction
`A+B+C rarr` Products, is given by
`r = -(dA)/(dt) = k[A]^(1//2)[B]^(1//3)[C]^(1//4)`
The order of a reaction is given by

A

1

B

2

C

13/12

D

5/4

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of the reaction given by the rate equation: \[ r = -\frac{dA}{dt} = k[A]^{\frac{1}{2}}[B]^{\frac{1}{3}}[C]^{\frac{1}{4}} \] we follow these steps: ### Step 1: Identify the powers of concentration terms The rate expression includes the concentrations of reactants A, B, and C raised to certain powers: - The power of A is \( \frac{1}{2} \) - The power of B is \( \frac{1}{3} \) - The power of C is \( \frac{1}{4} \) ### Step 2: Sum the powers To find the overall order of the reaction, we need to sum the powers of all the concentration terms: \[ \text{Order} = \left(\frac{1}{2}\right) + \left(\frac{1}{3}\right) + \left(\frac{1}{4}\right) \] ### Step 3: Find a common denominator The least common multiple (LCM) of the denominators 2, 3, and 4 is 12. We will convert each fraction to have this common denominator: - \( \frac{1}{2} = \frac{6}{12} \) - \( \frac{1}{3} = \frac{4}{12} \) - \( \frac{1}{4} = \frac{3}{12} \) ### Step 4: Add the fractions Now we can add these fractions together: \[ \text{Order} = \frac{6}{12} + \frac{4}{12} + \frac{3}{12} = \frac{6 + 4 + 3}{12} = \frac{13}{12} \] ### Conclusion Thus, the overall order of the reaction is: \[ \text{Order} = \frac{13}{12} \] ### Final Answer The order of the reaction is \( \frac{13}{12} \). ---
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