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Physisorption...

Physisorption

A

High specificty

B

Irreversibility

C

Non-specificity

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
C
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The correct statement(s) pertaining to the adsorption of a gas on a solid surface is(are) (i) adsorption is always exothermic (ii) physisorption may transform into chemsisorption transform into chemisorption at high temperature (iii) physisorption increases with increasing temperature but chemisorption decreases with increasing temperature . (iv) chemisorption is more exothermic than physisorption , however it is very slow due to higher energy of activation.

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Column - I and Column - II contains four emtries each. Entries of Column -I are to be matched with some entries of Column - II . One or more than one entries of Column -I may have the matching with the same entries of Column - II. {:("column-I","column-II"),("(A) Chemisorption","(P) Not specific and decreases with temperature "),("(B) physisorption",(Q) "sepecific and increases with temperature"),("(C) Desorption of a solute on liquid surface","(R) Increases the surface tension of the liquid "),("(D)Adsorption of a solute on a liquid ","(S) Decreases the surface tension of the liquid "):}

How many of the following quantities show increase in their value of increasing temperature? a. Extent of physisorption of gases on solids. b. Electrical conductivity of an electrolyte solution. c. Electrical conductivity of an electrolyte solution. d. Ionic product of water. e. Vapour pressure of a pure and liquid. f. Vapour pressure of an ideal solution which follows Rault's law, (keeping composition same) g. Solubility of gases in liquids. h. Reducing power of carbon monoxide for extraction of metals Correct answer:

each question contain STATEMENT-1(Assertion ) and STATEMENT - 2 (reason). examine the statement carefully and work the correct answer accoridng to the instructions given below : STATEMENT-1: More heat evolved in physiorpiton than in chemisorption. STATEMENT-2: Molecules of adsorbate and adsorbent are held by van der Waal's forces in physisorption and by chemical bonds in chemisorption.

Fill in the blanks by putting appropriate choices. During adsorption there is _______ in enthalpy and _______ in the entropy of a system by adsorption is a spontaneous process and thus DeltaG must be ________. Rate of physisorption ________ with increase in pressure.

Adsorption is the tendency of accumulation of molecular species at the surface of solid or liquid. Depending upon the nature of bonds or forces of attraction between adsorbate and adsorbent. It is classofied between physisorption and chemisorption. Which of the following characteristics is not correct for physical adsorption?

Adsorption is the tendency of accumulation of molecular species at the surface of solid or liquid. Depending upon the nature of bonds or forces of attraction between adsorbate and adsorbent. It is classofied between physisorption and chemisorption. Which of the following gases is adsorbed most by activated charcoal?

Adsorption is the tendency of accumulation of molecular species at the surface of solid or liquid. Depending upon the nature of bonds or forces of attraction between adsorbate and adsorbent. It is classofied between physisorption and chemisorption. Which of the following statements are correct? (More than one correct)