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Following reactions take place during ex...

Following reactions take place during extraction of gold
`4Au+8CN^(-)+ 2H_(2)O + O_(2) to 4[Au(CN)_(2)]^(-)+ 4OH^(-)`
`2[Au(CN)_(2)]^(-) + Zn to 2Au + [Zn(CN)_(4)]^(2-)`
Zinc in the extraction of gold acts as a/an

A

oxidising agent

B

flux

C

reducing agent

D

decomposing agent

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AI Generated Solution

The correct Answer is:
To determine the role of zinc in the extraction of gold as described in the given reactions, we can analyze the reactions step by step. ### Step 1: Analyze the First Reaction The first reaction is: \[ 4Au + 8CN^- + 2H_2O + O_2 \rightarrow 4[Au(CN)_2]^- + 4OH^- \] In this reaction, gold (Au) is reacting with cyanide ions (CN^-) and oxygen (O_2) to form a complex ion \([Au(CN)_2]^-\). Here, gold is being oxidized from its elemental state (0 oxidation state) to a +1 oxidation state in the complex. ### Step 2: Analyze the Second Reaction The second reaction is: \[ 2[Au(CN)_2]^- + Zn \rightarrow 2Au + [Zn(CN)_4]^{2-} \] In this reaction, the complex ion \([Au(CN)_2]^-\) reacts with zinc (Zn). In this process, the gold is reduced back to its elemental state (0 oxidation state), while zinc is oxidized from 0 to +2 oxidation state. ### Step 3: Determine the Role of Zinc Since zinc is being oxidized (its oxidation state increases from 0 to +2), it is acting as a reducing agent. A reducing agent donates electrons to another substance, causing that substance to be reduced. In this case, zinc donates electrons to gold, reducing it from a +1 oxidation state in the complex to 0 in its elemental form. ### Conclusion Thus, in the extraction of gold, zinc acts as a **reducing agent**. ### Final Answer Zinc in the extraction of gold acts as a reducing agent. ---
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