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In the metallurgy of aluminium,...

In the metallurgy of aluminium,

A

`Al^(3+)` is oxidised to `Al_((s))`

B

graphite anode is oxidised to carbon monoxide and carbon dioxide.

C

oxidation state of oxygen changes in the reaction at anode

D

oxidation state of oxygen change in the overall reaction involved in the process.

Text Solution

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The correct Answer is:
### Step-by-Step Solution: 1. **Understanding the Process**: The metallurgy of aluminum primarily involves the Hall-Héroult process, where aluminum oxide (Al₂O₃) is reduced to aluminum metal. This process requires an electrolytic cell. 2. **Components of the Electrolytic Cell**: In the Hall-Héroult process, the main components include: - **Electrolyte**: A mixture of Al₂O₃ and a flux like Na₃AlF₆ or CaF₂, which lowers the melting point and increases conductivity. - **Electrodes**: A carbon cathode and a graphite anode. 3. **Reactions at the Electrodes**: - **At the Cathode**: Aluminum ions (Al³⁺) are reduced to aluminum metal (Al). \[ \text{Al}^{3+} + 3e^- \rightarrow \text{Al (s)} \] - **At the Anode**: The carbon anode is oxidized, producing carbon monoxide (CO) and carbon dioxide (CO₂). \[ \text{C (s)} + 2\text{O}^{2-} \rightarrow \text{CO (g)} + 2\text{O}^{2-} \] \[ \text{C (s)} + \text{O}^{2-} \rightarrow \text{CO}_2 (g) + 4\text{e}^- \] 4. **Analyzing the Options**: - **Option 1**: "Al³⁺ is oxidized to aluminum solid." This is incorrect because Al³⁺ is reduced, not oxidized. - **Option 2**: "Graphite anode is oxidized to carbon monoxide and carbon dioxide." This is correct as the anode undergoes oxidation. - **Option 3**: "Oxidation state of oxygen changes in the reaction at the anode." This is incorrect; the oxidation state of oxygen remains -2 in both CO and CO₂. - **Option 4**: "Oxidation state of oxygen changes in the overall reaction involved in the process." This is also incorrect for the same reason as option 3. 5. **Conclusion**: The only correct statement is option 2. Therefore, the answer is that the graphite anode is oxidized to carbon monoxide and carbon dioxide.

### Step-by-Step Solution: 1. **Understanding the Process**: The metallurgy of aluminum primarily involves the Hall-Héroult process, where aluminum oxide (Al₂O₃) is reduced to aluminum metal. This process requires an electrolytic cell. 2. **Components of the Electrolytic Cell**: In the Hall-Héroult process, the main components include: - **Electrolyte**: A mixture of Al₂O₃ and a flux like Na₃AlF₆ or CaF₂, which lowers the melting point and increases conductivity. - **Electrodes**: A carbon cathode and a graphite anode. ...
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