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Which of the following transition metal ...

Which of the following transition metal ions is colourless ?

A

`V^(2+)`

B

`Cr^(3+)`

C

`Zn^(2+)`

D

`Ti^(3+)`

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AI Generated Solution

The correct Answer is:
To determine which transition metal ion is colorless, we need to analyze the electronic configurations of the given ions and check for the presence of unpaired electrons. Transition metal ions are typically colored due to the presence of unpaired electrons in their d-orbitals. If an ion has no unpaired electrons, it will be colorless. ### Step-by-Step Solution: 1. **Understand the Requirement for Color**: - Transition metal ions are colored if they have unpaired electrons. Conversely, if they have all paired electrons, they are colorless. 2. **Analyze Each Ion**: - **Vanadium (V²⁺)**: - Original electronic configuration: [Ar] 3d³ 4s² - For V²⁺, we remove two electrons (from 4s and one from 3d): - Configuration: 3d³ - Unpaired electrons: 3 (hence, colored) - **Chromium (Cr³⁺)**: - Original electronic configuration: [Ar] 3d⁵ 4s¹ - For Cr³⁺, we remove three electrons (two from 4s and one from 3d): - Configuration: 3d³ - Unpaired electrons: 3 (hence, colored) - **Zinc (Zn²⁺)**: - Original electronic configuration: [Ar] 3d¹⁰ 4s² - For Zn²⁺, we remove two electrons (from 4s): - Configuration: 3d¹⁰ - Unpaired electrons: 0 (hence, colorless) - **Titanium (Ti³⁺)**: - Original electronic configuration: [Ar] 3d² 4s² - For Ti³⁺, we remove three electrons (two from 4s and one from 3d): - Configuration: 3d¹ - Unpaired electrons: 1 (hence, colored) 3. **Conclusion**: - The only ion that has no unpaired electrons is **Zinc (Zn²⁺)**, which is therefore colorless. ### Final Answer: **Zinc (Zn²⁺) is the colorless transition metal ion.** ---

To determine which transition metal ion is colorless, we need to analyze the electronic configurations of the given ions and check for the presence of unpaired electrons. Transition metal ions are typically colored due to the presence of unpaired electrons in their d-orbitals. If an ion has no unpaired electrons, it will be colorless. ### Step-by-Step Solution: 1. **Understand the Requirement for Color**: - Transition metal ions are colored if they have unpaired electrons. Conversely, if they have all paired electrons, they are colorless. 2. **Analyze Each Ion**: ...
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NCERT FINGERTIPS ENGLISH-THE D- AND F- BLOCK ELEMENTS -Assertion And Reason
  1. Which of the following transition metal ions is colourless ?

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  2. Assertion : Zn, Cd and Hg are not regarded as transition elements. R...

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  3. Assertion : In transition elements radii of 5d series are virtually th...

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  4. Assertion (A) Cu^(2+) iodide is not known. Reason (R ) Cu^(2+) oxidi...

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  5. Assertion : Cr^(2+) is reducing and Mn^(3+) is oxidising. Reason : C...

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  6. STATEMENT-1: The highest oxidation state of chromium in its compounds ...

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  7. Assertion : The ability of oxygen to stabilize high oxidation states e...

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  8. Assertion : Copper dissolves in dilute nitric acid but not in dilute H...

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  9. Assertion : In the series Sc to Zn, the enthalpy of atomisation of zin...

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  10. Assertion : Magnetic moment of Mn^(2+) is less than Cr^(2+) Reason: ...

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  11. Assertion : Cr(VI) in the form of dichromate in acidic medium is a str...

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  12. Assertion : In acidic medium, K2Cr2O7 exists as Cr2O7^(2-) (orange) wh...

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  13. Assertion : Iron(III) catalyses the reaction between iodide and persul...

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  14. Assertion : KMNO4 acts as an oxidising agent in acidic, basic or neutr...

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  15. Assertion : Zr and Hf occur together in nature andare difficult to sep...

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  16. Assertion : Ce^(4+) is good analytical reagent. Reason: Ce^(4+) has ...

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