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If M is the element of actinoid series, ...

If M is the element of actinoid series, the degree of complex formation decrease in the order

A

`M^(4+) gt M^(3+) gtMO_2^(2+) gt MO_2^(+)`

B

`MO_2^(+) gt MO_2^(2+) gt M^(3+) gt M^(4+)`

C

`M^(4+) gt MO_2^(2+) gt M^(3+) gt MO_2^(+)`

D

`MO_2^(2+) lt MO_2^(+) lt M^(3+) gt M^(3+)`

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The correct Answer is:
To solve the question regarding the degree of complex formation of an element M from the actinoid series, we need to analyze the charges on the metal ions and their implications on complex formation. ### Step-by-Step Solution: 1. **Identify the Charges of Metal Ions**: - The actinoid series includes elements that can exhibit multiple oxidation states. For element M, we consider the common oxidation states: M^4+, M^3+, Mo2^2+, and Mo2+. 2. **Understand the Relationship Between Charge and Size**: - The degree of complex formation is influenced by the charge and size of the metal ion. Generally, a higher charge leads to a smaller ionic size, which enhances the ability to form complexes. 3. **Establish the Order of Complex Formation**: - The order of complex formation is determined by the effective charge and size of the metal ions: - M^4+ has the highest charge (+4), leading to a high degree of complex formation. - Mo2^2+ has a charge of +6 (since it can be considered as M^6+), which is also significant, but the overall size might be larger compared to M^4+. - M^3+ has a charge of +3, which is lower than M^4+ and Mo2^2+. - Mo2+ has the lowest charge (+2), leading to the least degree of complex formation. 4. **Correct Order of Complex Formation**: - Based on the analysis, the correct order of decreasing degree of complex formation is: - M^4+ > Mo2^2+ > M^3+ > Mo2+ 5. **Conclusion**: - Therefore, the final answer to the question is that the degree of complex formation decreases in the order: M^4+ > Mo2^2+ > M^3+ > Mo2+.

To solve the question regarding the degree of complex formation of an element M from the actinoid series, we need to analyze the charges on the metal ions and their implications on complex formation. ### Step-by-Step Solution: 1. **Identify the Charges of Metal Ions**: - The actinoid series includes elements that can exhibit multiple oxidation states. For element M, we consider the common oxidation states: M^4+, M^3+, Mo2^2+, and Mo2+. 2. **Understand the Relationship Between Charge and Size**: ...
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