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Which of the following ligands will not ...

Which of the following ligands will not show chelation ?

A

EDTA

B

DMG

C

Ethane-1, 2- diamine

D

`SCN^(-)`

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The correct Answer is:
To determine which ligand will not show chelation, we need to understand the concept of chelation and the types of ligands involved in coordination chemistry. ### Step-by-Step Solution: 1. **Understand Chelation**: - Chelation occurs when a ligand forms multiple bonds with a metal ion, resulting in a ring-like structure. This is important for the stability of the complex. 2. **Identify Ligands**: - Ligands can be classified based on their denticity (the number of donor atoms that can bind to a central metal atom). - Monodentate ligands have only one donor atom and can form only one bond with the metal ion. - Bidentate ligands can form two bonds, and polydentate ligands can form multiple bonds. 3. **Determine Ligand Types**: - In the given options, identify which ligands are monodentate and which are bidentate or polydentate. - For example, thiocyanate (SCN⁻) is a monodentate ligand because it can only attach to the metal through one atom (the sulfur or nitrogen). 4. **Conclusion**: - Since monodentate ligands cannot form ring structures with metal ions, they do not exhibit the chelation effect. - Therefore, the ligand that will not show chelation is thiocyanate (SCN⁻). ### Final Answer: The ligand that will not show chelation is **thiocyanate (SCN⁻)**. ---

To determine which ligand will not show chelation, we need to understand the concept of chelation and the types of ligands involved in coordination chemistry. ### Step-by-Step Solution: 1. **Understand Chelation**: - Chelation occurs when a ligand forms multiple bonds with a metal ion, resulting in a ring-like structure. This is important for the stability of the complex. 2. **Identify Ligands**: ...
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NCERT FINGERTIPS ENGLISH-COORDINATION COMPOUNDS -Assertion And Reason
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  3. Assertion : The complex K(3) [Cr(C(2)O(4))(3)] when present in aqueous...

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  4. Assertion : N(CH(2)CH(2)NH(2))(3) and EDTA are examples of polydentate...

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  5. Assertion : Coordination number of Fe and Co in [Fe(C(2) O(4))(3)]^(3-...

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  6. Assertion : [Co(NH(3))(5)Br]SO(4) gives white precipitate with barium ...

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  7. Assertion : Tetrahedral complexes having two different types of uniden...

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  8. Assertion : In a coordination entity [PtCl(2)(en)(2)]^(2+) only the ci...

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  9. Assertion : Inner orbital complexes are low spin complexes . Reason...

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  10. Assertion : [Fe(H(2)O)(6)]^(2+) is sp^(3) d^(2) hybridised and paramag...

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  11. Assertion : In tetrahedral complexes low spin configuration are rarel...

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  12. Assertion : [Ti(H(2)O)(6)]Cl(3) on heating becomes colourless . Reas...

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  13. Assertion : According to crystal field theory , during complex formati...

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  14. [Fe(H2O)6]^(3+) is strongly paramagnetic whereas [Fe(CN)6]^(3-) is wea...

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  15. Assertion : K(2)[Ni(EDTA)] is more stable than K(3)[Al(C(2)O(4))(3)]. ...

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  16. Assertion : Geometrical isomerism is also called cis-trans isomerism ....

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