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Which of the following does not depict t...

Which of the following does not depict the correct , name of the compound ?

A

`K_(2) [Zn(OH)_(4)]` : Potassium tetrahydroxozincate (II)

B

`[Co(NH_(3))_(5)CO_(3)]Cl:` Pentaammine carbonatochlorocobaltate(III)

C

`Na_(3)[Co(NO_(2))_(6)] :` Sodium hexanitrocobaltate (III)

D

`K_(3)[Cr(CN)_(6)]`: Potassium hexacyanochromate(III)

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the following coordination compounds does not have the correct name, we will analyze each option step by step. ### Step 1: Analyze the first compound - K2Zn(OH)4 - **Formula**: K2Zn(OH)4 - **Cation**: K+ (Potassium) - **Anion**: Zn(OH)4^2- (Zincate) - **Naming**: Since the anion is derived from hydroxide, it will end with "ate". The correct name is potassium tetrahydroxozincate(II). - **Conclusion**: This name is correct. ### Step 2: Analyze the second compound - [Co(NH3)5Cl]Cl2 - **Formula**: [Co(NH3)5Cl]Cl2 - **Cation**: [Co(NH3)5Cl]^2+ (Cobalt complex) - **Anion**: Cl^- - **Naming**: The cation is a complex ion and should not end with "ate". The correct name is pentaamminechlorocobalt(III) chloride. - **Conclusion**: This name is incorrect because it should not end with "ate". ### Step 3: Analyze the third compound - Na3[Co(NO2)6] - **Formula**: Na3[Co(NO2)6] - **Cation**: Na+ (Sodium) - **Anion**: [Co(NO2)6]^3- (Cobalt complex) - **Naming**: The anion is derived from nitro, and since it is a complex anion, it will end with "ate". The correct name is sodium hexanitrocobalt(III). - **Conclusion**: This name is correct. ### Step 4: Analyze the fourth compound - K3[Cr(CN)6] - **Formula**: K3[Cr(CN)6] - **Cation**: K+ (Potassium) - **Anion**: [Cr(CN)6]^3- (Chromate complex) - **Naming**: The anion is derived from cyanide, and it will end with "ate". The correct name is potassium hexacyanochromate(III). - **Conclusion**: This name is correct. ### Final Conclusion: The second compound, [Co(NH3)5Cl]Cl2, has the incorrect name. It should be named pentaamminechlorocobalt(III) chloride, not ending with "ate".

To determine which of the following coordination compounds does not have the correct name, we will analyze each option step by step. ### Step 1: Analyze the first compound - K2Zn(OH)4 - **Formula**: K2Zn(OH)4 - **Cation**: K+ (Potassium) - **Anion**: Zn(OH)4^2- (Zincate) - **Naming**: Since the anion is derived from hydroxide, it will end with "ate". The correct name is potassium tetrahydroxozincate(II). - **Conclusion**: This name is correct. ...
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NCERT FINGERTIPS ENGLISH-COORDINATION COMPOUNDS -Assertion And Reason
  1. Which of the following does not depict the correct , name of the compo...

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  2. Assertion : Aqueous solution of the compound CoCl(3) * 4NH(3) when tre...

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  3. Assertion : The complex K(3) [Cr(C(2)O(4))(3)] when present in aqueous...

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  4. Assertion : N(CH(2)CH(2)NH(2))(3) and EDTA are examples of polydentate...

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  5. Assertion : Coordination number of Fe and Co in [Fe(C(2) O(4))(3)]^(3-...

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  6. Assertion : [Co(NH(3))(5)Br]SO(4) gives white precipitate with barium ...

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  7. Assertion : Tetrahedral complexes having two different types of uniden...

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  8. Assertion : In a coordination entity [PtCl(2)(en)(2)]^(2+) only the ci...

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  9. Assertion : Inner orbital complexes are low spin complexes . Reason...

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  10. Assertion : [Fe(H(2)O)(6)]^(2+) is sp^(3) d^(2) hybridised and paramag...

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  11. Assertion : In tetrahedral complexes low spin configuration are rarel...

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  12. Assertion : [Ti(H(2)O)(6)]Cl(3) on heating becomes colourless . Reas...

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  13. Assertion : According to crystal field theory , during complex formati...

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  14. [Fe(H2O)6]^(3+) is strongly paramagnetic whereas [Fe(CN)6]^(3-) is wea...

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  15. Assertion : K(2)[Ni(EDTA)] is more stable than K(3)[Al(C(2)O(4))(3)]. ...

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  16. Assertion : Geometrical isomerism is also called cis-trans isomerism ....

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