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Hexaamminenickel(II) hexanitrocobaltate(...

Hexaamminenickel(II) hexanitrocobaltate(III) can be written as

A

`[Ni(NH_(3))_(6)]_(2) [Co(NO_(2))_(6)]_(3)`

B

`[Ni(NH_(3))_(6)]_(3) [Co(NO_(2))_(6)]_(2)`

C

`[Ni(NH_(3))_(6)][Co(NO_(2))_(6)]`

D

`[Ni(NH_(3))_(6)(NO_(2))_(6)]Co`

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The correct Answer is:
To write the formula for Hexaamminenickel(II) hexanitrocobaltate(III), we will follow these steps: ### Step 1: Identify the components of the coordination compound - The first part of the name is "Hexaamminenickel(II)", which indicates that we have a nickel ion (Ni) coordinated with six ammonia (NH3) ligands. - The second part is "hexanitrocobaltate(III)", indicating a cobalt ion (Co) coordinated with six nitro (NO2) ligands and in the +3 oxidation state. ### Step 2: Write the formula for Hexaamminenickel(II) - The nickel ion has a +2 oxidation state, and each ammonia ligand is neutral. Therefore, the formula for Hexaamminenickel(II) is: \[ \text{Ni(NH}_3\text{)}_6^{2+} \] ### Step 3: Write the formula for hexanitrocobaltate(III) - The cobalt ion has a +3 oxidation state, and each nitro ligand has a -1 charge. Therefore, the formula for hexanitrocobaltate(III) is: \[ \text{Co(NO}_2\text{)}_6^{3-} \] ### Step 4: Combine the two components - Now, we combine the two parts. The overall charge of the complex must be neutral. The Hexaamminenickel(II) has a charge of +2, and hexanitrocobaltate(III) has a charge of -3. To balance the charges, we need to consider the stoichiometry: - We need three units of Hexaamminenickel(II) to balance the -3 charge from one unit of hexanitrocobaltate(III). ### Step 5: Write the complete formula - The complete formula for the coordination compound is: \[ \text{[Ni(NH}_3\text{)}_6]^{2+} \text{[Co(NO}_2\text{)}_6]^{3-} \] - To represent the entire compound, we write it as: \[ \text{Ni(NH}_3\text{)}_6^{3} \text{Co(NO}_2\text{)}_6^{2} \] ### Final Answer The final formula for Hexaamminenickel(II) hexanitrocobaltate(III) is: \[ \text{[Ni(NH}_3\text{)}_6]^{3} \text{[Co(NO}_2\text{)}_6]^{2} \]
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NCERT FINGERTIPS ENGLISH-COORDINATION COMPOUNDS -Assertion And Reason
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  7. Assertion : Tetrahedral complexes having two different types of uniden...

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  8. Assertion : In a coordination entity [PtCl(2)(en)(2)]^(2+) only the ci...

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  9. Assertion : Inner orbital complexes are low spin complexes . Reason...

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  10. Assertion : [Fe(H(2)O)(6)]^(2+) is sp^(3) d^(2) hybridised and paramag...

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  11. Assertion : In tetrahedral complexes low spin configuration are rarel...

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  12. Assertion : [Ti(H(2)O)(6)]Cl(3) on heating becomes colourless . Reas...

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  13. Assertion : According to crystal field theory , during complex formati...

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  14. [Fe(H2O)6]^(3+) is strongly paramagnetic whereas [Fe(CN)6]^(3-) is wea...

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  15. Assertion : K(2)[Ni(EDTA)] is more stable than K(3)[Al(C(2)O(4))(3)]. ...

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  16. Assertion : Geometrical isomerism is also called cis-trans isomerism ....

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