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Mark the incorrect statement ....

Mark the incorrect statement .

A

Inner orbital (low spin) complexes involve `d^(2) sp^(3)` hybridisation .

B

Outer orbital (high spin) complexes involve `sp^(3) d^(2)` hybridisation .

C

Tetrahedral complexes generally involve `dsp^(2)` hybridisation .

D

Stereoisomerism involves geometrical and optical isomerism .

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question of identifying the incorrect statement regarding coordination compounds, we will analyze each statement one by one. ### Step-by-Step Solution: 1. **Statement 1: Inner orbital complexes involve d²sp³ hybridization.** - **Analysis:** Inner orbital complexes are those that utilize the 3d orbitals for bonding. The hybridization d²sp³ is indeed characteristic of inner orbital complexes. Therefore, this statement is **correct**. 2. **Statement 2: Outer orbital complexes involve sp³d² hybridization.** - **Analysis:** Outer orbital complexes do not use the 3d orbitals for bonding. Instead, they typically involve hybridizations like sp³d². Thus, this statement is also **correct**. 3. **Statement 3: Tetrahedral complexes generally involve dsp² hybridization.** - **Analysis:** Tetrahedral complexes are characterized by sp³ hybridization, not dsp². The dsp² hybridization is associated with square planar complexes. Therefore, this statement is **incorrect**. 4. **Statement 4: Stereoisomers involve geometrical and optical isomers.** - **Analysis:** Stereoisomers indeed include both geometrical isomers (cis/trans) and optical isomers (enantiomers). Hence, this statement is **correct**. ### Conclusion: The incorrect statement among the options provided is **Statement 3**. Therefore, the answer is **C**. ---

To solve the question of identifying the incorrect statement regarding coordination compounds, we will analyze each statement one by one. ### Step-by-Step Solution: 1. **Statement 1: Inner orbital complexes involve d²sp³ hybridization.** - **Analysis:** Inner orbital complexes are those that utilize the 3d orbitals for bonding. The hybridization d²sp³ is indeed characteristic of inner orbital complexes. Therefore, this statement is **correct**. 2. **Statement 2: Outer orbital complexes involve sp³d² hybridization.** ...
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