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The increasing order of the crystal fiel...

The increasing order of the crystal field splitting power of some common ligands is

A

`NH_(3) lt Cl^(-) lt CN^(-) lt F^(-) lt CO lt H_(2)O`

B

`F^(-) lt Cl^(-) lt NH_(3) lt CN^(-) lt H_(2)O lt CO`

C

`Cl^(-) lt F^(-) lt H_(2)O lt NH_(3) lt CN^(-) lt CO`

D

`CO lt CN^(-) lt NH_(3) lt H_(2)O lt F^(-) lt Cl^(-)`

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The correct Answer is:
To determine the increasing order of crystal field splitting power of some common ligands, we can refer to the spectrochemical series, which ranks ligands based on their ability to split the d-orbitals in transition metal complexes. The ligands that cause a greater splitting of the d-orbitals are considered stronger field ligands, while those that cause less splitting are weaker field ligands. ### Step-by-Step Solution: 1. **Understand the Spectrochemical Series**: The spectrochemical series is a list of ligands arranged in order of their field strength. Strong field ligands cause a large splitting of the d-orbitals, while weak field ligands cause a small splitting. 2. **Identify Common Ligands**: Some common ligands include: - CO (carbon monoxide) - CN⁻ (cyanide ion) - PPh₃ (triphenylphosphine) - NO₂⁻ (nitrite ion) - en (ethylenediamine) - NH₃ (ammonia) - pyridine - NCS⁻ (thiocyanate ion) - H₂O (water) - C₂O₄²⁻ (oxalate ion) - OH⁻ (hydroxide ion) - F⁻ (fluoride ion) - NO₃⁻ (nitrate ion) - Cl⁻ (chloride ion) 3. **Rank the Ligands According to their Field Strength**: Based on the spectrochemical series, the ligands can be ranked as follows (from strongest to weakest): - CO > CN⁻ > PPh₃ > NO₂⁻ > en > NH₃ > pyridine > NCS⁻ > H₂O > C₂O₄²⁻ > OH⁻ > F⁻ > NO₃⁻ > Cl⁻ 4. **Determine the Increasing Order of Crystal Field Splitting Power**: To find the increasing order, we need to list the ligands from weakest to strongest field strength: - Cl⁻ < NO₃⁻ < F⁻ < OH⁻ < C₂O₄²⁻ < H₂O < NCS⁻ < pyridine < NH₃ < en < NO₂⁻ < PPh₃ < CN⁻ < CO 5. **Select the Correct Option**: Based on the increasing order identified, the correct option from the provided choices will be the one that lists the ligands in the order from Cl⁻ to CO. ### Final Answer: The increasing order of the crystal field splitting power of some common ligands is: **Cl⁻ < NO₃⁻ < F⁻ < OH⁻ < C₂O₄²⁻ < H₂O < NCS⁻ < pyridine < NH₃ < en < NO₂⁻ < PPh₃ < CN⁻ < CO**

To determine the increasing order of crystal field splitting power of some common ligands, we can refer to the spectrochemical series, which ranks ligands based on their ability to split the d-orbitals in transition metal complexes. The ligands that cause a greater splitting of the d-orbitals are considered stronger field ligands, while those that cause less splitting are weaker field ligands. ### Step-by-Step Solution: 1. **Understand the Spectrochemical Series**: The spectrochemical series is a list of ligands arranged in order of their field strength. Strong field ligands cause a large splitting of the d-orbitals, while weak field ligands cause a small splitting. 2. **Identify Common Ligands**: ...
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