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Explain why hexacayano complexe of metal...

Explain why hexacayano complexe of metals in their +2 oxidation state are usually yellow , but the corresponding hexa aqua compounds are often blue or green .

A

hexacyano complexes absorb orange or red light thus appear yellow while hexaaqua complexes absorb indigo thus appear yellow

B

hexacyano complexes absorb indigo thus appearing yellow while hexaaqua complexes absorb orange or red light thus appear blue or green

C

hexacyano complexes absorb yellow light while hexaaqua complexes absorb blue light

D

`CN^(-)` ions are yellow in colour while aqua ions are blue or green in colour .

Text Solution

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The correct Answer is:
D
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NCERT FINGERTIPS ENGLISH-COORDINATION COMPOUNDS -Assertion And Reason
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  9. Assertion : Inner orbital complexes are low spin complexes . Reason...

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  10. Assertion : [Fe(H(2)O)(6)]^(2+) is sp^(3) d^(2) hybridised and paramag...

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  11. Assertion : In tetrahedral complexes low spin configuration are rarel...

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  12. Assertion : [Ti(H(2)O)(6)]Cl(3) on heating becomes colourless . Reas...

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