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Both geometrical and optical isomerism a...

Both geometrical and optical isomerism are shown by

A

`[Co(en)_(2) Cl_(2)]^(+)`

B

`[Co(NH_(3)_(5)Cl]^(2+)`

C

`[Co(NH_(3))_(4)Cl_(2)]^(+)`

D

`[Cr("ox")_(3)]^(3-)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which coordination compound exhibits both geometrical and optical isomerism, we can analyze the options provided. Here's a step-by-step solution: ### Step 1: Understanding Isomerism - **Geometrical Isomerism** occurs when there are different spatial arrangements of ligands around a central metal atom, typically seen in coordination compounds with square planar or octahedral geometries. - **Optical Isomerism** arises when a compound can exist in two forms that are mirror images of each other (enantiomers) and cannot be superimposed on one another. ### Step 2: Analyzing the Options 1. **Option 1**: Check if it can show both types of isomerism. 2. **Option 2**: Check if it can show both types of isomerism. 3. **Option 3**: Check if it can show both types of isomerism. 4. **Option 4**: Check if it can show both types of isomerism. ### Step 3: Evaluating Each Option - **Option 4**: It shows optical isomerism but does not exhibit geometrical isomerism. Thus, it cannot be the answer. - **Option 3**: It shows only geometrical isomerism. Therefore, it cannot be the answer. - **Option 2**: It does not show any isomerism. Hence, it cannot be the answer. - **Option 1**: It shows both geometrical and optical isomerism. This is the correct option. ### Step 4: Identifying the Isomers - For the compound in **Option 1**, we can illustrate: - **Geometrical Isomers**: These include the **cis** and **trans** forms. - **Optical Isomers**: These are the non-superimposable mirror images of the cis form. ### Conclusion The coordination compound in **Option 1** is the one that exhibits both geometrical and optical isomerism. ---

To determine which coordination compound exhibits both geometrical and optical isomerism, we can analyze the options provided. Here's a step-by-step solution: ### Step 1: Understanding Isomerism - **Geometrical Isomerism** occurs when there are different spatial arrangements of ligands around a central metal atom, typically seen in coordination compounds with square planar or octahedral geometries. - **Optical Isomerism** arises when a compound can exist in two forms that are mirror images of each other (enantiomers) and cannot be superimposed on one another. ### Step 2: Analyzing the Options 1. **Option 1**: Check if it can show both types of isomerism. ...
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